Mayer, B., Jung, S., Brauns, M. and Muenker, C. (2018). The role of mantle-hybridization and crustal contamination in the petrogenesis of lithospheric mantle-derived alkaline rocks: constraints from Os and Hf isotopes. Contrib. Mineral. Petrol., 173 (6). NEW YORK: SPRINGER. ISSN 1432-0967

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Abstract

The Rhon area as part of the Central European Volcanic Province (CEVP) hosts an unusual suite of Tertiary 24-Ma old hornblende-bearing alkaline basalts that provide insights into melting and fractionation processes within the lithospheric mantle. These chemically primitive to slightly evolved and isotopically (Sr, Nd, Pb) depleted basalts have slightly lower Hf isotopic compositions than respective other CEVP basalts and Os isotope compositions more radiogenic than commonly observed for continental intraplate alkaline basalts. These highly radiogenic initial Os-187/Os-188 ratios (0.268-0.892) together with their respective Sr-Nd-Pb isotopic compositions are unlikely to result from crustal contamination alone, although a lack of Os data for lower crustal rocks from the area and limited data for CEVP basalts or mantle xenoliths preclude a detailed evaluation. Similarly, melting of the same metasomatized subcontinental lithospheric mantle as inferred for other CEVP basalts alone is also unlikely, based on only moderately radiogenic Os isotope compositions obtained for upper mantle xenoliths from elsewhere in the province. Another explanation for the combined Nd, Sr and Os isotope data is that the lavas gained their highly radiogenic Os isotope composition through a mantle hybridization, metasomatism process. This model involves a mafic lithospheric component, such as an intrusion of a sublithospheric primary alkaline melt or a melt derived from subducted oceanic material, sometime in the past into the lithospheric mantle where it metasomatized the ambient mantle. Later at 24 Ma, thermal perturbations during rifting forced the isotopically evolved parts of the mantle together with the peridotitic ambient mantle to melt. This yielded a package of melts with highly correlated Re/Os ratios and radiogenic Os isotope compositions. Subsequent movement through the crust may have further altered the Os isotope composition although this effect is probably minor for the majority of the samples based on radiogenic Nd and unradiogenic Sr isotope composition of the lavas. If the radiogenic Os isotope composition can be explained by a mantle-hybridization and metasomatism model, the isotopic compositions of the hornblende basalts can be satisfied by ca. 5-25% addition of the mafic lithospheric component to an asthenospheric alkaline magma. Although a lack of isotope data for all required endmembers make this model somewhat speculative, the results show that the Re-Os isotope system in continental basalts is able to distinguish between crustal contamination and derivation of continental alkaline lavas from isotopically evolved peridotitic lithosphere that was contaminated by mafic material in the past and later remelted during rifting. The Hf isotopic compositions are slightly less radiogenic than in other alkaline basalts from the province and indicate the derivation of the lavas from low Lu-Hf parts of the lithospheric mantle. The new Os and Hf isotope data constrain a new light of the nature of such metasomatizing agents, at least for these particular rocks, which represent within the particular volcanic complex the first product of the volcanism.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Mayer, B.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Jung, S.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Brauns, M.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Muenker, C.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-185470
DOI: 10.1007/s00410-018-1473-2
Journal or Publication Title: Contrib. Mineral. Petrol.
Volume: 173
Number: 6
Date: 2018
Publisher: SPRINGER
Place of Publication: NEW YORK
ISSN: 1432-0967
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
EUROPEAN VOLCANIC PROVINCE; CENOZOIC RIFT SYSTEM; SUB-OCEANIC MANTLE; CENTRAL GERMANY; TRACE-ELEMENT; PERIDOTITE XENOLITHS; CONTINENTAL-CRUST; SUBDUCTION ZONES; ND ISOTOPE; LU-HFMultiple languages
Geochemistry & Geophysics; MineralogyMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/18547

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