Martin-Drumel, M. A., van Wijngaarden, J., Zingsheim, O., Lewen, F., Harding, M. E., Schlemmer, S. and Thorwirth, S. (2015). Millimeter- and submillimeter-wave spectroscopy of disulfur dioxide, OSSO. J. Mol. Spectrosc., 307. S. 33 - 40. SAN DIEGO: ACADEMIC PRESS INC ELSEVIER SCIENCE. ISSN 1096-083X

Full text not available from this repository.

Abstract

The millimeter-wave spectrum of the cis conformer of disulfur dioxide, cis-OSSO, has been recorded in this study in the ranges 70-120 GHz and 340-500 GHz. Transitions of its second most abundant isotopologue, (OSSO)-S-34, have also been observed. The species was produced in a radio frequency discharge through flowing SO2. An improved set of molecular parameters has been derived from the newly recorded data, allowing for accurate predictions throughout the millimeter-wave region and into the submillimeter-wave domain. Quantum-chemical calculations at the coupled-cluster level of theory have also been performed, providing an accurate set of structural parameters of this species for comparison with experimentally derived values. (C) 2014 Elsevier Inc. All rights reserved.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Martin-Drumel, M. A.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
van Wijngaarden, J.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Zingsheim, O.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Lewen, F.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Harding, M. E.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Schlemmer, S.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Thorwirth, S.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-417633
DOI: 10.1016/j.jms.2014.11.007
Journal or Publication Title: J. Mol. Spectrosc.
Volume: 307
Page Range: S. 33 - 40
Date: 2015
Publisher: ACADEMIC PRESS INC ELSEVIER SCIENCE
Place of Publication: SAN DIEGO
ISSN: 1096-083X
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; RICH OXIDES SNO; EQUILIBRIUM STRUCTURE; 2ND DERIVATIVES; ROTATIONAL SPECTROSCOPY; MICROWAVE-SPECTRUM; MANY-BODY; ORION KL; S2O2Multiple languages
Physics, Atomic, Molecular & Chemical; SpectroscopyMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/41763

Downloads

Downloads per month over past year

Altmetric

Export

Actions (login required)

View Item View Item