Tran, Uyen P. N., Oss, Giulia, Breugst, Martin ORCID: 0000-0003-0950-8858, Detmar, Eric, Pace, Domenic P., Liyanto, Kevin and Nguyen, Thanh V. (2019). Carbonyl-Olefin Metathesis Catalyzed by Molecular Iodine. ACS Catal., 9 (2). S. 912 - 927. WASHINGTON: AMER CHEMICAL SOC. ISSN 2155-5435

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Abstract

The carbonyl-olefin metathesis reaction could facilitate rapid functional group interconversion and allow construction of complicated organic structures. Herein, we demonstrate that elemental iodine, a very simple catalyst, can efficiently promote this chemical transformation under mild reaction conditions. Our mechanistic studies revealed intriguing aspects of the activation mode via molecular iodine and the iodonium ion that could change the previously established perception of catalyst and substrate design for the carbonyl-olefin metathesis reaction.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Tran, Uyen P. N.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Oss, GiuliaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Breugst, MartinUNSPECIFIEDorcid.org/0000-0003-0950-8858UNSPECIFIED
Detmar, EricUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Pace, Domenic P.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Liyanto, KevinUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Nguyen, Thanh V.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-157716
DOI: 10.1021/acscatal.8b03769
Journal or Publication Title: ACS Catal.
Volume: 9
Number: 2
Page Range: S. 912 - 927
Date: 2019
Publisher: AMER CHEMICAL SOC
Place of Publication: WASHINGTON
ISSN: 2155-5435
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
ENOL ETHERS; ACTIVATION; ENERGIES; MECHANISM; ALCOHOLS; PYRIDINE; ESTER; SALTSMultiple languages
Chemistry, PhysicalMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/15771

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