Universität zu Köln

Obert, J. Christina, Scholz, D., Felis, T., Lippold, J., Jochum, Klaus P. and Andreae, Meinrat O. (2019). Improved constraints on open-system processes in fossil reef corals by combined Th/U, Pa/U and Ra/Th dating: A case study from Aqaba, Jordan. Geochim. Cosmochim. Acta, 245. S. 459 - 479. OXFORD: PERGAMON-ELSEVIER SCIENCE LTD. ISSN 1872-9533

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Abstract

Here we present Th-230/U, Pa-231/U as well as( 226)Ra/ Th-230 isotope ratios from five fossil reef corals of Last Interglacial origin from the Gulf of Aqaba, Northern Red Sea. The results show clear evidence for open-system behaviour with strongly elevated delta U-234 values and U concentrations indicating post-depositional U addition. The combined application of all isotope systems enables us to better constrain the nature and timing of the open-system processes than only based on the Th-230/U data. Quantitative modelling of the diagenetic processes allowed us to reproduce the trends in the isotope ratios. Two of the five corals were probably affected by two separate phases of U addition with different delta U-234 values. The trends observed for two other corals can be explained by U addition followed by U loss. The fifth coral shows signs of both U gain and loss at the same time in the more recent past. The timing of the diagenetic processes is remarkably similar for the five corals and can be constrained to approx. 1 and 6 thousand years (ka) and 100 and 102 ka after coral growth, respectively. Based on the modelling results, we suggest that conventional Pa-231/Th-230 ages provide the best estimate for the true age of four of the five corals, which range from 109.1 to 114.1 ka. This implies a late Last Interglacial time of deposition. For the fifth coral, the most reliable age estimate is the conventional( 230)Th/U age of one of the subsamples (117.3 ka), based on a concordia diagram for all subsamples. The timing of the modelled open-system processes suggests that the early event of U addition was associated with interaction of the corals with U-234-enriched seawater or saline groundwater. The later open-system event can be described as U redistribution within the coral reef, since some corals apparently lost U while others gained U. The timing of the second event is broadly consistent with the Bolling-Allerod interstadial, which was probably characterised by enhanced wetness in this typically hyper-arid region. (C) 2018 Elsevier Ltd. All rights reserved.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Obert, J. Christina UNSPECIFIED UNSPECIFIED UNSPECIFIED Scholz, D. UNSPECIFIED UNSPECIFIED UNSPECIFIED Felis, T. UNSPECIFIED UNSPECIFIED UNSPECIFIED Lippold, J. UNSPECIFIED UNSPECIFIED UNSPECIFIED Jochum, Klaus P. UNSPECIFIED UNSPECIFIED UNSPECIFIED Andreae, Meinrat O. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-159268
DOI:	10.1016/j.gca.2018.11.024
Journal or Publication Title:	Geochim. Cosmochim. Acta
Volume:	245
Page Range:	S. 459 - 479
Date:	2019
Publisher:	PERGAMON-ELSEVIER SCIENCE LTD
Place of Publication:	OXFORD
ISSN:	1872-9533
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language MELTWATER PULSE 1B; SEA-LEVEL; U-TH; MASS-SPECTROMETRY; URANIUM; DIAGENESIS; AGES; ACCURATE; PRECISE; ISOTOPE Multiple languages Geochemistry & Geophysics Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/15926