Jusko, Pavol, Simon, Aude ORCID: 0000-0002-2315-9490, Banhatti, Shreyak, Bruenken, Sandra and Joblin, Christine ORCID: 0000-0003-1561-6118 (2018). Direct Evidence of the Benzylium and Tropylium Cations as the Two Long-Lived Isomers of C7H7+. ChemPhysChem, 19 (23). S. 3182 - 3186. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1439-7641

Full text not available from this repository.

Abstract

Disentangling the isomeric structure of C7H7+ is a longstanding experimental issue. We report here the full mid-infrared vibrational spectrum of C7H7+ tagged with Ne obtained with infrared-predissociation spectroscopy at 10 K. Saturation depletion measurements were used to assign the contribution of benzylium and tropylium isomers and demonstrate that no other isomer is involved. Recorded spectral features compare well with density functional theory calculations. This opens perspectives for a better understanding and control of the formation paths leading to either tropylium or benzylium ions.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Jusko, PavolUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Simon, AudeUNSPECIFIEDorcid.org/0000-0002-2315-9490UNSPECIFIED
Banhatti, ShreyakUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Bruenken, SandraUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Joblin, ChristineUNSPECIFIEDorcid.org/0000-0003-1561-6118UNSPECIFIED
URN: urn:nbn:de:hbz:38-162401
DOI: 10.1002/cphc.201800744
Journal or Publication Title: ChemPhysChem
Volume: 19
Number: 23
Page Range: S. 3182 - 3186
Date: 2018
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1439-7641
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
VIBRATIONAL SPECTROSCOPY; TOLUENE; IONS; PATHWAYS; SPECTRAMultiple languages
Chemistry, Physical; Physics, Atomic, Molecular & ChemicalMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/16240

Downloads

Downloads per month over past year

Altmetric

Export

Actions (login required)

View Item View Item