Universität zu Köln

Mueller, Daniel S., Werner, Veronika, Akyol, Sema, Schmalz, Hans-Guenther ORCID: 0000-0003-0489-1827 and Marek, Ilan (2017). Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives. Org. Lett., 19 (15). S. 3970 - 3974. WASHINGTON: AMER CHEMICAL SOC. ISSN 1523-7052

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Abstract

Herein, we report the first enantio- and diastereoselective addition of stereodefined vinyl organometallic reagents to cyclopropenes. The operationally simple tandem hydroalumination and copper-catalyzed vinylmetalation allows for the unique access of a diverse set of enantioenriched vinylcyclopropane derivatives.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Mueller, Daniel S. UNSPECIFIED UNSPECIFIED UNSPECIFIED Werner, Veronika UNSPECIFIED UNSPECIFIED UNSPECIFIED Akyol, Sema UNSPECIFIED UNSPECIFIED UNSPECIFIED Schmalz, Hans-Guenther UNSPECIFIED orcid.org/0000-0003-0489-1827 UNSPECIFIED Marek, Ilan UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-221951
DOI:	10.1021/acs.orglett.7b01661
Journal or Publication Title:	Org. Lett.
Volume:	19
Number:	15
Page Range:	S. 3970 - 3974
Date:	2017
Publisher:	AMER CHEMICAL SOC
Place of Publication:	WASHINGTON
ISSN:	1523-7052
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Organic Chemistry
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CYCLOPROPANATION REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CONJUGATE ADDITION; LIGANDS; CYCLOPROPENES; ALKENYL; REARRANGEMENT; OLEFINS; FR-900848; ALCOHOLS Multiple languages Chemistry, Organic Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/22195