Zhang, Qiangqiang, Wu, Liangliang ORCID: 0000-0002-5434-0786, Cao, Xiaoyan
ORCID: 0000-0002-3438-575X, Chen, Xuebo, Fang, Weihai and Dolg, Michael
ORCID: 0000-0002-0538-0837
(2017).
Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes.
Angew. Chem.-Int. Edit., 56 (27).
S. 7986 - 7991.
WEINHEIM:
WILEY-V C H VERLAG GMBH.
ISSN 1521-3773
Abstract
The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum-chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet-quintet intersystem crossing on the basis of spin-orbit coupling among the sublevels of the involved states.
Item Type: | Journal Article | ||||||||||||||||||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-227436 | ||||||||||||||||||||||||||||
DOI: | 10.1002/anie.201701575 | ||||||||||||||||||||||||||||
Journal or Publication Title: | Angew. Chem.-Int. Edit. | ||||||||||||||||||||||||||||
Volume: | 56 | ||||||||||||||||||||||||||||
Number: | 27 | ||||||||||||||||||||||||||||
Page Range: | S. 7986 - 7991 | ||||||||||||||||||||||||||||
Date: | 2017 | ||||||||||||||||||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||||||||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||||||||||||||||||
ISSN: | 1521-3773 | ||||||||||||||||||||||||||||
Language: | English | ||||||||||||||||||||||||||||
Faculty: | Faculty of Mathematics and Natural Sciences | ||||||||||||||||||||||||||||
Divisions: | Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Theoretical Chemistry | ||||||||||||||||||||||||||||
Subjects: | no entry | ||||||||||||||||||||||||||||
Uncontrolled Keywords: |
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Refereed: | Yes | ||||||||||||||||||||||||||||
URI: | http://kups.ub.uni-koeln.de/id/eprint/22743 |
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