Heim, Leo E., Konnerth, Hannelore and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2016). The Prospecting Shortcut to an Old Molecule: Formaldehyde Synthesis at Low Temperature in Solution. ChemSusChem, 9 (20). S. 2905 - 2908. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1864-564X

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Abstract

Over 30megatons of formaldehyde are required per year and industrially produced through three high-temperature gas-phase processes: i)natural gas reforming to syngas, ii)methanol synthesis, and iii)partial oxidation to formaldehyde with limited selectivity. In vast contrast to these energy-intensive oxidative and dehydrogenative methods, a reductive top-down methodology using CO2 and CO as carbon source would be desirable and is not very well present in the literature for more than 100years. The key to success is the reaction performance in liquid solution in water or methanol at low temperature.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Heim, Leo E.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Konnerth, HanneloreUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Prechtl, Martin H. G.UNSPECIFIEDorcid.org/0000-0003-2155-8006UNSPECIFIED
URN: urn:nbn:de:hbz:38-258262
DOI: 10.1002/cssc.201601043
Journal or Publication Title: ChemSusChem
Volume: 9
Number: 20
Page Range: S. 2905 - 2908
Date: 2016
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1864-564X
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CARBON-DIOXIDE; AQUEOUS-PHASE; HYDROGENATION; METHANOL; HYDROFORMYLATION; CATALYSTS; MONOXIDE; WATERMultiple languages
Chemistry, Multidisciplinary; Green & Sustainable Science & TechnologyMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/25826

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