Choi, Jong-Hoo ORCID: 0000-0001-7938-8420 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2015). Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions. ChemCatChem, 7 (6). S. 1023 - 1029. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1867-3899

Full text not available from this repository.

Abstract

The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Choi, Jong-HooUNSPECIFIEDorcid.org/0000-0001-7938-8420UNSPECIFIED
Prechtl, Martin H. G.UNSPECIFIEDorcid.org/0000-0003-2155-8006UNSPECIFIED
URN: urn:nbn:de:hbz:38-405882
DOI: 10.1002/cctc.201403047
Journal or Publication Title: ChemCatChem
Volume: 7
Number: 6
Page Range: S. 1023 - 1029
Date: 2015
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1867-3899
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CARBOXYLIC-ACID ESTERS; CATALYTIC-HYDROGENATION; INFRARED-SPECTRA; LIQUID-PHASE; BENZONITRILE; ALDEHYDES; REACTIVITY; REDUCTION; LIGANDS; KETONESMultiple languages
Chemistry, PhysicalMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/40588

Downloads

Downloads per month over past year

Altmetric

Export

Actions (login required)

View Item View Item