Choi, Jong-Hoo ORCID: 0000-0001-7938-8420 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2015). Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions. ChemCatChem, 7 (6). S. 1023 - 1029. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1867-3899
Full text not available from this repository.Abstract
The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.
Item Type: | Journal Article | ||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-405882 | ||||||||||||
DOI: | 10.1002/cctc.201403047 | ||||||||||||
Journal or Publication Title: | ChemCatChem | ||||||||||||
Volume: | 7 | ||||||||||||
Number: | 6 | ||||||||||||
Page Range: | S. 1023 - 1029 | ||||||||||||
Date: | 2015 | ||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||
ISSN: | 1867-3899 | ||||||||||||
Language: | English | ||||||||||||
Faculty: | Unspecified | ||||||||||||
Divisions: | Unspecified | ||||||||||||
Subjects: | no entry | ||||||||||||
Uncontrolled Keywords: |
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URI: | http://kups.ub.uni-koeln.de/id/eprint/40588 |
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