Universität zu Köln

Choi, Jong-Hoo ORCID: 0000-0001-7938-8420 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2015). Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions. ChemCatChem, 7 (6). S. 1023 - 1029. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1867-3899

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Abstract

The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Choi, Jong-Hoo UNSPECIFIED orcid.org/0000-0001-7938-8420 UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-410773
DOI:	10.1002/cctc.201403047
Journal or Publication Title:	ChemCatChem
Volume:	7
Number:	6
Page Range:	S. 1023 - 1029
Date:	2015
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1867-3899
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CARBOXYLIC-ACID ESTERS; CATALYTIC-HYDROGENATION; INFRARED-SPECTRA; LIQUID-PHASE; BENZONITRILE; ALDEHYDES; REACTIVITY; REDUCTION; LIGANDS; KETONES Multiple languages Chemistry, Physical Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/41077