Universität zu Köln

Gruene, Tim ORCID: 0000-0002-8873-4978, Sheldricle, George M., ZlatopolsIdybe, Boris D., Kozhushkovb, Sergei I. and de Meijereb, Armin (2014). Structure of Hormaomycin, a Naturally Occurring Cyclic Octadepsipeptide, in the Crystal. Z.Naturforsch.(B), 69 (9-10). S. 945 - 950. TUBINGEN: VERLAG Z NATURFORSCH. ISSN 1865-7117

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Abstract

The structure of hormaomycin has been determined in two crystals grown under different conditions, i. e. in the absence and in the presence of magnesium chloride. In both crystals, the macrocyclic hexadepsipeptide assumes a rather flat conformation, and the dipeptide side chain resides in the same equatorial plane. This is a significant difference in comparison with the compact bent conformation of hormaomycin in solution, as previously determined by an extensive NMR study.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Gruene, Tim UNSPECIFIED orcid.org/0000-0002-8873-4978 UNSPECIFIED Sheldricle, George M. UNSPECIFIED UNSPECIFIED UNSPECIFIED ZlatopolsIdybe, Boris D. UNSPECIFIED UNSPECIFIED UNSPECIFIED Kozhushkovb, Sergei I. UNSPECIFIED UNSPECIFIED UNSPECIFIED de Meijereb, Armin UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-426266
DOI:	10.5560/ZNB.2014-4116
Journal or Publication Title:	Z.Naturforsch.(B)
Volume:	69
Number:	9-10
Page Range:	S. 945 - 950
Date:	2014
Publisher:	VERLAG Z NATURFORSCH
Place of Publication:	TUBINGEN
ISSN:	1865-7117
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language PRECURSOR-DIRECTED BIOSYNTHESIS; BIOLOGICAL-ACTIVITIES; ANALOGS; DEPSIPEPTIDE; ELUCIDATION Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/42626