Asvany, Oskar and Schlemmer, Stephan ORCID: 0000-0002-1421-7281 (2021). Rotational action spectroscopy of trapped molecular ions. Phys. Chem. Chem. Phys., 23 (47). S. 26602 - 26623. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1463-9084

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Abstract

Rotational action spectroscopy is an experimental method in which rotational spectra of molecules, typically in the microwave to sub-mm-wave domain of the electromagnetic spectrum (similar to 1-1000 GHz), are recorded by action spectroscopy. Action spectroscopy means that the spectrum is recorded not by detecting the absorption of light by the molecules, but by the action of the light on the molecules, e.g., photon-induced dissociation of a chemical bond, a photon-triggered reaction, or photodetachment of an electron. Typically, such experiments are performed on molecular ions, which can be well controlled and mass-selected by guiding and storage techniques. Though coming with many advantages, the application of action schemes to rotational spectroscopy was hampered for a long time by the small energy content of a corresponding photon. Therefore, the first rotational action spectroscopic methods emerged only about one decade ago. Today, there exists a toolbox full of different rotational action spectroscopic schemes which are summarized in this review.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Asvany, OskarUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Schlemmer, StephanUNSPECIFIEDorcid.org/0000-0002-1421-7281UNSPECIFIED
URN: urn:nbn:de:hbz:38-562351
DOI: 10.1039/d1cp03975j
Journal or Publication Title: Phys. Chem. Chem. Phys.
Volume: 23
Number: 47
Page Range: S. 26602 - 26623
Date: 2021
Publisher: ROYAL SOC CHEMISTRY
Place of Publication: CAMBRIDGE
ISSN: 1463-9084
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
AB-INITIO CALCULATIONS; VIBRATIONAL PREDISSOCIATION SPECTROSCOPY; HIGH-RESOLUTION SPECTROSCOPY; SUBMILLIMETER-WAVE LINES; H STRETCHING VIBRATION; PURE QUANTUM STATES; INFRARED-SPECTRUM; PHOTODISSOCIATION SPECTRA; MICROWAVE SPECTROSCOPY; ELECTRONIC-SPECTRAMultiple languages
Chemistry, Physical; Physics, Atomic, Molecular & ChemicalMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/56235

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