Universität zu Köln

Maleki, Hajar ORCID: 0000-0002-2813-4700 and Huesing, Nicola (2021). Silica-silk fibroin hybrid (bio)aerogels: two-step versus one-step hybridization. J. Sol-Gel Sci. Technol., 98 (2). S. 430 - 439. NEW YORK: SPRINGER. ISSN 1573-4846

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Abstract

In this study, silk fibroin as a highly promising naturally occurring biopolymer extracted from silkworm cocoon is applied to mechanically reinforce silica aerogels. To this aim, two different approaches for the incorporation of silk fibroin into the silica network are compared: (1) a one-step acid catalyzed and (2) a two-step acid-base catalyzed sol-gel reaction. The total organosilane concentration, as well as the SF to silane mass fractions, regulated the hybridization process to proceed either through a one-step or two-step sol-gel reaction. In both processes, for an efficient chemical mixing the silk fibroin components with the silane phase, a silane coupling agent, 5-(trimethoxysilyl) pentanoic acid (TMSPA), comprising carboxylic acid groups and a pentyl hydrocarbon chain has been used. For a low organosilane content (3.4 mmol) along with a high SF to silane mass ratio (15-30%), the gelation of the silane and silk fibroin phases took place in a one-pot/one-step process in the presence of an acid catalyst in an entirely aqueous system. In the two-step synthesis approach, which was applied for high initial silane contents (17 mmol), and low SF to silane mass ratios (1-4%), first, the gelation of the silk fibroin phase was triggered by addition of an acid catalyst followed by a more pronounced condensation of the silane catalyzed by the addition of the base. Both synthesis approaches led to materials with promising mechanical properties-being 1) the one-step process resulting in gels with much better compressibility (up to 70% of strain), low density (0.17-0.22 g cm(-3)) and three orders of magnitude improvement in the Young's modulus (13.5 MPa) compared to that of the pristine silica aerogel but with rather high shrinkage (30-40%). The two-step process in principle could result in the hybrid aerogel with interesting bulk density (0.17-0.28 g cm(-3)) with lower shrinkage (10%), but the resultant aerogel was stiff and fragile. Also, both approaches led to a significant reduction in the time required to prepare strong hybrid aerogels compared to conventional hybrid polymer-silica aerogels with the utilization of an entirely aqueous synthesis approach for a wide range of applications.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Maleki, Hajar UNSPECIFIED orcid.org/0000-0002-2813-4700 UNSPECIFIED Huesing, Nicola UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-569953
DOI:	10.1007/s10971-019-04933-4
Journal or Publication Title:	J. Sol-Gel Sci. Technol.
Volume:	98
Number:	2
Page Range:	S. 430 - 439
Date:	2021
Publisher:	SPRINGER
Place of Publication:	NEW YORK
ISSN:	1573-4846
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language Materials Science, Ceramics Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/56995