Universität zu Köln

Pasqualini, Leonard C., Huppertz, Hubert ORCID: 0000-0002-2098-6087 and Bruns, Joern (2019). M[B-2(SO4)(4)] (M = Mn, Zn)-Syntheses and Crystal Structures of Two New Phyllosilicate Analogue Borosulfates. Inorganics, 7 (12). BASEL: MDPI. ISSN 2304-6740

Full text not available from this repository.

Abstract

Borosulfates are a rapidly expanding class of silicate analogue materials, where the structural diversity is expected to be at least as large as known for silicates. However, borosulfates with cross-linking of the anionic network into two or even three dimensions are still very rare. Herein, we present two new representatives with phyllosilicate analogue topology. Through solvothermal reactions of ZnO and MnCl2 center dot 4H(2)O with boric acid in oleum (65% SO3), we obtained single-crystals of Mn[B-2(SO4)(4)] (monoclinic, P2(1)/n, Z = 2, a = 8.0435(4), b = 7.9174(4), c = 9.3082(4) angstrom, beta = 110.94(1)degrees, V = 553.63(5) angstrom(3)) and Zn[B-2(SO4)(4)] (monoclinic, P2(1)/n, Z = 2, a = 7.8338(4), b = 8.0967(4), c = 9.0399(4) angstrom, beta = 111.26(1)degrees, V = 534.36(5) angstrom(3)). The crystal structures reveal layer-like anionic networks with alternating vierer- and zwolfer-rings formed exclusively by corner-linked (SO4)- and (BO4)-tetrahedra.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Pasqualini, Leonard C. UNSPECIFIED UNSPECIFIED UNSPECIFIED Huppertz, Hubert UNSPECIFIED orcid.org/0000-0002-2098-6087 UNSPECIFIED Bruns, Joern UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-125555
DOI:	10.3390/inorganics7120145
Journal or Publication Title:	Inorganics
Volume:	7
Number:	12
Date:	2019
Publisher:	MDPI
Place of Publication:	BASEL
ISSN:	2304-6740
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language ALKALI; BOROPHOSPHATES Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/12555