Bohr, Christoph ORCID: 0000-0002-8427-8346, Pfeiffer, Markus, Oz, Senol, von Toperczer, Florian, Lepcha, Ashish, Fischer, Thomas, Schuetz, Markus, Lindfors, Klas and Mathur, Sanjay ORCID: 0000-0003-2765-2693 (2019). Electrospun Hybrid Perovskite Fibers-Flexible Networks of One-Dimensional Semiconductors for Light-Harvesting Applications. ACS Appl. Mater. Interfaces, 11 (28). S. 25163 - 25170. WASHINGTON: AMER CHEMICAL SOC. ISSN 1944-8252

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Abstract

Thin-film organic inorganic hybrid perovskite (MeNH3PbI3) solar cells have displayed remarkably high photoconversion efficiencies, making their net-shaping as flexible device elements desirable for a number of applications. Simulations show greatly enhanced light absorption in perovskite fibers in comparison to their thin-film counterparts, which demand the processing of hybrid perovskites in the one-dimensional morphology. We report here on the single-step fabrication of MeNH3PbI3 nanofibers on a customized electrospinning process performed under inert conditions. Our results demonstrate reproducible synthesis of electrospun fiber mats in which the fiber dimensions were tailored by adjusting the polymer (PVP) content. Photoluminescence studies on the perovskite fibers revealed a blue shift of the emission peak possibly due to strain or charge confinement effects. The hybrid perovskite nanofibers offer promising applications in flexible and stretchable opto electronics.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Bohr, ChristophUNSPECIFIEDorcid.org/0000-0002-8427-8346UNSPECIFIED
Pfeiffer, MarkusUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Oz, SenolUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
von Toperczer, FlorianUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Lepcha, AshishUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Fischer, ThomasUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Schuetz, MarkusUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Lindfors, KlasUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Mathur, SanjayUNSPECIFIEDorcid.org/0000-0003-2765-2693UNSPECIFIED
URN: urn:nbn:de:hbz:38-134990
DOI: 10.1021/acsami.9b05700
Journal or Publication Title: ACS Appl. Mater. Interfaces
Volume: 11
Number: 28
Page Range: S. 25163 - 25170
Date: 2019
Publisher: AMER CHEMICAL SOC
Place of Publication: WASHINGTON
ISSN: 1944-8252
Language: English
Faculty: Faculty of Mathematics and Natural Sciences
Divisions: Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Inorganic Chemistry
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
SOLAR-CELLS; COMPOSITE; FABRICATION; NANOFIBERSMultiple languages
Nanoscience & Nanotechnology; Materials Science, MultidisciplinaryMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/13499

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