Universität zu Köln

Gudenschwager, Marit, Christoffers, Jens and Wickleder, Mathias S. ORCID: 0000-0002-8864-4227 (2019). Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni-3[CH(SO3)(3)](2)(NMP)(8)}. Z.Naturforsch.(B), 74 (1). S. 27 - 32. BERLIN: WALTER DE GRUYTER GMBH. ISSN 1865-7117

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Abstract

The reaction of Ni(OH)(2) and methanetrisulfonic acid trihydrate CH(SO3H)(3)center dot 3H(2)O (H(3)MTA center dot 3H(2)O) in N-methyl-pyrrolidone (NMP) leads to the trinuclear complex {Ni-3[MTA](2)(NMP)(8)] (triclinic, P (1) over bar, Z=1, a =946.25(3), b= 1073.24(3), c= 1518.27(4) pm, alpha = 72.193(2), beta = 87398(2), gamma = 89.389(2)degrees, V = 1466.49(7) x 10(6) pm(3)). The structural features of the methanetrisulfonate anions are tripodal as well as chelating coordination of the Ni2+ ions. The thermal analysis has shown that the compound is first losing NMP molecules and that the solvent-free methanetrisulfonate finally decomposes yielding Ni3S2.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Gudenschwager, Marit UNSPECIFIED UNSPECIFIED UNSPECIFIED Christoffers, Jens UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED orcid.org/0000-0002-8864-4227 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-140489
DOI:	10.1515/znb-2018-0152
Journal or Publication Title:	Z.Naturforsch.(B)
Volume:	74
Number:	1
Page Range:	S. 27 - 32
Date:	2019
Publisher:	WALTER DE GRUYTER GMBH
Place of Publication:	BERLIN
ISSN:	1865-7117
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Inorganic Chemistry
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language 1,4-BENZENEDISULFONIC ACID; COORDINATION POLYMERS; METHANESULFONIC-ACID; CRYSTAL-STRUCTURE Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/14048