Nemec, Ivan ORCID: 0000-0001-9630-3169, Matulkova, Irena ORCID: 0000-0002-9289-6400, Held, Peter, Kroupa, Jan, Nemec, Petr ORCID: 0000-0001-6867-5942, Li, Dongxu, Bohaty, Ladislav and Becker, Petra (2017). Crystal growth, crystal structure, vibrational spectroscopy, linear and nonlinear optical properties of guanidinium phosphates. Opt. Mater., 69. S. 420 - 432. AMSTERDAM: ELSEVIER. ISSN 1873-1252

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Abstract

Of the three guanidinium phosphates GuH(2)PO(4) (space group P2(1)/c), Gu(2)HPO(4) center dot H2O (space group P (4) over bar2(1) c) and Gu(3)PO(4)center dot H2O (space group Cc) crystal structures and a vibrational spectroscopy study are presented. Large single crystals of GuH(2)PO(4) and Gu(2)HPO(4)center dot H2O are grown. Refractive indices and their dispersion in the wavelength range 365 nm - 1083 nm are determined and used for the analysis of phase matching conditions for collinear SHG in the case of the non-centrosymmetric crystals of Gu(2)HPO(4)center dot H2O. The crystals are not phase-matchable within their transmission range. Both independent components of the SHG tensor of Gu(2)HPO(4) center dot H2O, determined by the Maker fringe method, are given, with d(14) = 0.23 pm/V and d(36) = 0.22 pm/V. In addition, the thermal stability and the anisotropy of thermal expansion of GuH(2)PO(4) and Gu(2)HPO(4) center dot H2O is reported. (C) 2017 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Nemec, IvanUNSPECIFIEDorcid.org/0000-0001-9630-3169UNSPECIFIED
Matulkova, IrenaUNSPECIFIEDorcid.org/0000-0002-9289-6400UNSPECIFIED
Held, PeterUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Kroupa, JanUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Nemec, PetrUNSPECIFIEDorcid.org/0000-0001-6867-5942UNSPECIFIED
Li, DongxuUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Bohaty, LadislavUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Becker, PetraUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-226834
DOI: 10.1016/j.optmat.2017.04.012
Journal or Publication Title: Opt. Mater.
Volume: 69
Page Range: S. 420 - 432
Date: 2017
Publisher: ELSEVIER
Place of Publication: AMSTERDAM
ISSN: 1873-1252
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
MONOHYDRATE; POLARIZATION; TRANSITIONMultiple languages
Materials Science, Multidisciplinary; OpticsMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/22683

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