Spanka, Marina, Mansfeldt, Tim and Bialucha, Ruth (2016). Influence of Natural and Accelerated Carbonation of Steel Slags on Their Leaching Behavior. Steel Res. Int., 87 (6). S. 798 - 811. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1869-344X

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Abstract

The influence of natural and accelerated carbonation on the leaching behavior of a basic oxygen furnace slag (BOS), electric arc furnace slag from carbon steel production (EAF C), and electric arc furnace slag from high-alloy/stainless steel production (EAF S) has been investigated in this study. The carbonation reaction is examined using two experimental series: (i) outdoor-exposure tests; and (ii) accelerated carbonation treatments in the laboratory. The achieved leaching results for the exposed steel slags show a distinct increase in Si and V concentrations and a decrease of Ca, with lower pH, due to carbonation. The other elements (Al, Cr, F, and Mo) react differently to carbonation depending on the mineral binding. However, the achieved results show that the German LAGA emplacement category can be improved from Z 2, for restricted applications with defined safeguarding measures, to Z 1 restricted open applications, due to carbonation. With regard to the storage of carbon dioxide (CO2) in slags and CO2 reduction of the atmosphere, the EAF S appears to be best suited for carbonation, because this slag reveals the highest CO2 uptake. Moreover, for this slag type significant decreases of the leached amount of Al, Ca, Cr, and Mo could be achieved.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Spanka, MarinaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Mansfeldt, TimUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Bialucha, RuthUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-272695
DOI: 10.1002/srin.201500370
Journal or Publication Title: Steel Res. Int.
Volume: 87
Number: 6
Page Range: S. 798 - 811
Date: 2016
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1869-344X
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CO2 SEQUESTRATION; STORAGE; PRESSURE; PRODUCTSMultiple languages
Metallurgy & Metallurgical EngineeringMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/27269

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