Universität zu Köln

van Gerven, David and Wickleder, Mathias S. ORCID: 0000-0002-8864-4227 (2020). S6N2O15-A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid. Angew. Chem.-Int. Edit., 59 (39). S. 17169 - 17172. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3773

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Abstract

The reaction of hexachlorophosphazene, P3N3Cl6, with SO(3)leads to the new sulfur nitride oxide S6N2O15. The compound displays an extraordinarily low nitrogen content and exhibits a bicyclic cage structure according to the formulation N{S(O)(2)O(O)(2)S}(3)N, with both nitrogen atoms in trigonal planar coordination of sulfur atoms. Interestingly, the new nitride oxide can be also seen as the anhydride of nitrido-tris-sulfuric acid, N(SO3H)(3).

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code van Gerven, David UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED orcid.org/0000-0002-8864-4227 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-323939
DOI:	10.1002/anie.202005056
Journal or Publication Title:	Angew. Chem.-Int. Edit.
Volume:	59
Number:	39
Page Range:	S. 17169 - 17172
Date:	2020
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3773
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Inorganic Chemistry
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language RAY STRUCTURE-ANALYSIS; CRYSTAL-STRUCTURE; REDETERMINATION; REFINEMENT; COMPOUND; TRIOXIDE; RINGS Multiple languages Chemistry, Multidisciplinary Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/32393