van Gerven, David and Wickleder, Mathias S. ORCID: 0000-0002-8864-4227
(2020).
S6N2O15-A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid.
Angew. Chem.-Int. Edit., 59 (39).
S. 17169 - 17172.
WEINHEIM:
WILEY-V C H VERLAG GMBH.
ISSN 1521-3773
Abstract
The reaction of hexachlorophosphazene, P3N3Cl6, with SO(3)leads to the new sulfur nitride oxide S6N2O15. The compound displays an extraordinarily low nitrogen content and exhibits a bicyclic cage structure according to the formulation N{S(O)(2)O(O)(2)S}(3)N, with both nitrogen atoms in trigonal planar coordination of sulfur atoms. Interestingly, the new nitride oxide can be also seen as the anhydride of nitrido-tris-sulfuric acid, N(SO3H)(3).
Item Type: | Journal Article | ||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-323939 | ||||||||||||
DOI: | 10.1002/anie.202005056 | ||||||||||||
Journal or Publication Title: | Angew. Chem.-Int. Edit. | ||||||||||||
Volume: | 59 | ||||||||||||
Number: | 39 | ||||||||||||
Page Range: | S. 17169 - 17172 | ||||||||||||
Date: | 2020 | ||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||
ISSN: | 1521-3773 | ||||||||||||
Language: | English | ||||||||||||
Faculty: | Faculty of Mathematics and Natural Sciences | ||||||||||||
Divisions: | Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Inorganic Chemistry | ||||||||||||
Subjects: | no entry | ||||||||||||
Uncontrolled Keywords: |
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Refereed: | Yes | ||||||||||||
URI: | http://kups.ub.uni-koeln.de/id/eprint/32393 |
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