Breugst, Martin ORCID: 0000-0003-0950-8858 and Koenig, Jonas J. (2020). sigma-Hole Interactions in Catalysis. Eur. J. Org. Chem., 2020 (34). S. 5473 - 5488. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1099-0690

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Abstract

Noncovalent interactions like halogen, chalcogen, and pnictogen bonding are known for a very long time. During the last decade, these interactions have found different applications in catalysis. These forces are often called sigma-hole interactions which can be explained by the anisotropic distribution of the electron density around these atoms. In this MiniReview, we will present recent applications of halogen, chalcogen, and pnictogen bonding in catalysis and discuss experimental and computational investigations to gain more insights into the underlying mechanisms.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Breugst, MartinUNSPECIFIEDorcid.org/0000-0003-0950-8858UNSPECIFIED
Koenig, Jonas J.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-325635
DOI: 10.1002/ejoc.202000660
Journal or Publication Title: Eur. J. Org. Chem.
Volume: 2020
Number: 34
Page Range: S. 5473 - 5488
Date: 2020
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1099-0690
Language: English
Faculty: Faculty of Mathematics and Natural Sciences
Divisions: Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Organic Chemistry
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CENTER-DOT-N; CAMBRIDGE STRUCTURAL DATABASE; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; PNICOGEN BOND; ELECTRONEGATIVE SUBSTITUENTS; INTRAMOLECULAR COORDINATION; ORGANOSELENIUM CHEMISTRY; NONCOVALENT INTERACTIONS; DI(TERTIARY PHOSPHINES)Multiple languages
Chemistry, OrganicMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/32563

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