Universität zu Köln

Stoll, Christiane, van Gerven, David and Huppertz, Hubert (2020). Serendipitous formation of K15NaSn5F36. Z.Naturforsch.(B), 75 (3). S. 309 - 316. BERLIN: WALTER DE GRUYTER GMBH. ISSN 1865-7117

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Abstract

K15NaSn5F36 crystallizes in the hexagonal crystal system with space group P6(3)/m and lattice parameters of a = 1060.3(2) and c = 2011.9(4) pm. The unit-cell volume amounts to 1.9588(7) nm(3). Its fundamental building blocks are quasi-isolated [SnF6](2-) and [NaF6](5-) octahedra, which are imbedded into a matrix of potassium cations. Within the structure, these units form a layer-like arrangement consisting either of mixed [SnF6](2)(-)/[NaF6](5)(-) or pure [SnF6](2)(-) layers. The structural model was further confirmed by BLBS and CHARDI calculations.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Stoll, Christiane UNSPECIFIED UNSPECIFIED UNSPECIFIED van Gerven, David UNSPECIFIED UNSPECIFIED UNSPECIFIED Huppertz, Hubert UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-342542
DOI:	10.1515/znb-2019-0201
Journal or Publication Title:	Z.Naturforsch.(B)
Volume:	75
Number:	3
Page Range:	S. 309 - 316
Date:	2020
Publisher:	WALTER DE GRUYTER GMBH
Place of Publication:	BERLIN
ISSN:	1865-7117
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; PHOTOLUMINESCENCE; CONDUCTIVITY; FLUORIDES; TL Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/34254