Universität zu Köln

Deska, Jan ORCID: 0000-0003-4622-2365, Thiel, Daniel and Gianolio, Eleonora (2015). The Achmatowicz Rearrangement - Oxidative Ring Expansion of Furfuryl Alcohols. Synthesis, 47 (22). S. 3435 - 3451. STUTTGART: GEORG THIEME VERLAG KG. ISSN 1437-210X

Full text not available from this repository.

Abstract

Over the years, the oxidative ring enlargement of furfuryl alcohols, known as the Achmatowicz reaction, has been developed into a powerful and versatile synthetic tool for the preparation of 6-hydroxy-pyranones. This review provides a comprehensive collection of the various ways to perform Achmatowicz rearrangement reactions and explores the role of this ring-expansion process in contemporary organic synthesis. 1 Introduction 2 Classical Methods and Variants 3 Single-Electron-Transfer Oxidations 4 Metal-Catalyzed Ring Expansions 5 Photolytic Oxygenations 6 Enzymatic Transformations 7 Conclusions

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED Thiel, Daniel UNSPECIFIED UNSPECIFIED UNSPECIFIED Gianolio, Eleonora UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-387991
DOI:	10.1055/s-0035-1560345
Journal or Publication Title:	Synthesis
Volume:	47
Number:	22
Page Range:	S. 3435 - 3451
Date:	2015
Publisher:	GEORG THIEME VERLAG KG
Place of Publication:	STUTTGART
ISSN:	1437-210X
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language OXYGENATED NATURAL-PRODUCTS; ASYMMETRIC TOTAL-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; STEREOCONTROLLED SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; FURAN-DERIVATIVES; SINGLET-OXYGEN; ENANTIOSELECTIVE SYNTHESIS; ONE-POT; ENANTIOCONTROLLED SYNTHESIS Multiple languages Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/38799