Universität zu Köln

Heim, Leo E., Thiel, Daniel, Gedig, Christian, Deska, Jan ORCID: 0000-0003-4622-2365 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2015). Bioinduced Room-Temperature Methanol Reforming. Angew. Chem.-Int. Edit., 54 (35). S. 10308 - 10313. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3773

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Abstract

Imitating nature's approach in nucleophile-activated formaldehyde dehydrogenation, air-stable ruthenium complexes proved to be exquisite catalysts for the dehydrogenation of formaldehyde hydrate as well as for the transfer hydrogenation to unsaturated organic substrates at loadings as low as 0.5 mol%. Concatenation of the chemical hydrogen-fixation route with an oxidase-mediated activation of methanol gives an artificial methylotrophic in vitro metabolism providing methanol-derived reduction equivalents for synthetic hydrogenation purposes. Moreover, for the first time methanol reforming at room temperature was achieved on the basis of this bioinduced dehydrogenation path delivering hydrogen gas from aqueous methanol.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Heim, Leo E. UNSPECIFIED UNSPECIFIED UNSPECIFIED Thiel, Daniel UNSPECIFIED UNSPECIFIED UNSPECIFIED Gedig, Christian UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-396227
DOI:	10.1002/anie.201503737
Journal or Publication Title:	Angew. Chem.-Int. Edit.
Volume:	54
Number:	35
Page Range:	S. 10308 - 10313
Date:	2015
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3773
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language DEPENDENT FORMALDEHYDE DEHYDROGENASE; HYDROGEN-PRODUCTION; FORMIC-ACID; CARBON-DIOXIDE; ARTIFICIAL METALLOENZYMES; CATALYST; WATER; DECOMPOSITION; METABOLISM; COMPLEXES Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/39622