Thorwirth, Sven ORCID: 0000-0001-8200-6710, Kaiser, Ralf I., Crabtree, Kyle N. and McCarthy, Michael C. (2015). Spectroscopic and structural characterization of three silaisocyanides: exploring an elusive class of reactive molecules at high resolution. Chem. Commun., 51 (56). S. 11305 - 11309. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1364-548X
Full text not available from this repository.Abstract
Silaisocyanoacetylene, HCCNSi, silaisocyanodiacetylene, HC4NSi, and silaisocyanogen, NCNSi, have been identified spectroscopically for the first time. All three transient species were observed at high spectral resolution at centimeter wavelengths (5-40 GHz) by microwave spectroscopy. From detection of less abundant isotopic species and high-level quantum-chemical calculations, accurate empirical equilibrium structures have been derived for HCCNSi and NCNSi. All three molecules are promising candidates for future radio astronomical detection owing in part to large calculated dipole moments.
Item Type: | Journal Article | ||||||||||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-416335 | ||||||||||||||||||||
DOI: | 10.1039/c5cc02548f | ||||||||||||||||||||
Journal or Publication Title: | Chem. Commun. | ||||||||||||||||||||
Volume: | 51 | ||||||||||||||||||||
Number: | 56 | ||||||||||||||||||||
Page Range: | S. 11305 - 11309 | ||||||||||||||||||||
Date: | 2015 | ||||||||||||||||||||
Publisher: | ROYAL SOC CHEMISTRY | ||||||||||||||||||||
Place of Publication: | CAMBRIDGE | ||||||||||||||||||||
ISSN: | 1364-548X | ||||||||||||||||||||
Language: | English | ||||||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||||||
Subjects: | no entry | ||||||||||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/41633 |
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