Choi, Jong-Hoo ORCID: 0000-0001-7938-8420, Heim, Leo E., Ahrens, Mike and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2014). Selective conversion of alcohols in water to carboxylic acids by in situ generated ruthenium trans dihydrido carbonyl PNP complexes. Dalton Trans., 43 (46). S. 17248 - 17255. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1477-9234
Full text not available from this repository.Abstract
In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source. Applying a ruthenium dihydrogen based dehydrogenation catalyst for this cause, we investigated the effect of water on the catalytic dehydrogenation process of alcohols. Using 1 mol% of the catalyst we report up to high yields. Moreover, we isolated key intermediates which most likely play a role in the catalytic cycle. One of the intermediates was identified as a trans dihydrido carbonyl complex which is generated in situ in the catalytic process.
Item Type: | Journal Article | ||||||||||||||||||||
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URN: | urn:nbn:de:hbz:38-449378 | ||||||||||||||||||||
DOI: | 10.1039/c4dt01634c | ||||||||||||||||||||
Journal or Publication Title: | Dalton Trans. | ||||||||||||||||||||
Volume: | 43 | ||||||||||||||||||||
Number: | 46 | ||||||||||||||||||||
Page Range: | S. 17248 - 17255 | ||||||||||||||||||||
Date: | 2014 | ||||||||||||||||||||
Publisher: | ROYAL SOC CHEMISTRY | ||||||||||||||||||||
Place of Publication: | CAMBRIDGE | ||||||||||||||||||||
ISSN: | 1477-9234 | ||||||||||||||||||||
Language: | English | ||||||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||||||
Subjects: | no entry | ||||||||||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/44937 |
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