Kulikov, Vladislav and Meyer, Gerd (2014). Hexa- to Octamolybdate Rearrangement leads to the New Coordination Polymer [Ag(PhCN)(thb)](4)[beta-Mo8O26](PhCN)(2). Z. Anorg. Allg. Chem., 640 (1). S. 19 - 23. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749
Full text not available from this repository.Abstract
Polyoxomolybdates tend to re-agglomerate to -octamolybdate upon reaction with Ag+ under hydrothermal conditions and in organic solvents. Consistent with this tendency, a new coordination polymer [Ag(PhCN)(thb)](4)[-Mo8O26](PhCN)(2) (thb = theobromine) (1) was obtained and characterized by single crystal XRD, powder XRD, DTA/TG, IR, UV/Vis, and elemental analysis. 1 is a one-dimensional coordination polymer, in which octamolybdate anions are joined by [Ag(PhCN)(thb)](+) cations along the crystallographic a axis. A firm network of intermolecular interactions, especially between self-pairing thb ligands, interlinks these chains. Salt 1 is turned into MoO2 and Ag upon thermolysis in an intramolecular redox reaction.
Item Type: | Journal Article | ||||||||||||
Creators: |
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URN: | urn:nbn:de:hbz:38-450978 | ||||||||||||
DOI: | 10.1002/zaac.201300391 | ||||||||||||
Journal or Publication Title: | Z. Anorg. Allg. Chem. | ||||||||||||
Volume: | 640 | ||||||||||||
Number: | 1 | ||||||||||||
Page Range: | S. 19 - 23 | ||||||||||||
Date: | 2014 | ||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||
ISSN: | 1521-3749 | ||||||||||||
Language: | English | ||||||||||||
Faculty: | Unspecified | ||||||||||||
Divisions: | Unspecified | ||||||||||||
Subjects: | no entry | ||||||||||||
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URI: | http://kups.ub.uni-koeln.de/id/eprint/45097 |
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