Universität zu Köln

Sutorius, Stefan, Hanrath, Michael and Bruns, Joern (2022). Be[B-2(SO4)(4)] - A Borosulfate Exhibiting Ino- and Phyllosilicate Analogue Topology. Eur. J. Inorg. Chem., 2022 (11). WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1099-0682

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Abstract

Borosulfates are a constantly expanding class of silicate analogue compounds. The anionic substructures are composed of vertex-connected (BO4)- and (SO4)-tetrahedra and feature topologies of monomeric, oligomeric, and polymeric anions. The latter resemble typical motifs of ino-, phyllo- and tectosilicates but none of the hitherto known borosulfates exhibits two different anion topologies within one structure. However, this is very rare even for the homopolyanionic silicates. Be[B-2(SO4)(4)] is the first borosulfate featuring anionic chains and layers within one structure and both substructures are interconnected by (BeO4)-tetrahedra. DFT calculations complement the experimental studies and help to describe the bonding situation of the Be-O bonds.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Sutorius, Stefan UNSPECIFIED UNSPECIFIED UNSPECIFIED Hanrath, Michael UNSPECIFIED UNSPECIFIED UNSPECIFIED Bruns, Joern UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-660080
DOI:	10.1002/ejic.202200009
Journal or Publication Title:	Eur. J. Inorg. Chem.
Volume:	2022
Number:	11
Date:	2022
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1099-0682
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CRYSTAL; FREQUENCIES; ALKALI Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66008