Universität zu Köln

Sperling, Joseph M., Beck, Nicholas ORCID: 0000-0001-5687-192X, Scheibe, Benjamin ORCID: 0000-0002-4665-6289, Bai, Zhuanling, Brannon, Jacob ORCID: 0000-0001-7786-127X, Gomez-Martinez, Daniela, Groedler, Dennis, Johnson, Jason A., Lin, Xinsong ORCID: 0000-0002-0605-3029, Rotermund, Brian M. and Albrecht-Schoenzart, Thomas E. (2022). Synthesis, characterization, and high-pressure studies of a 3D berkelium(iii) carboxylate framework material. Chem. Commun., 58 (13). S. 2200 - 2204. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1364-548X

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Abstract

A berkelium(iii) mellitate, Bk-2[C-6(CO2)(6)](H2O)(8)center dot 2H(2)O, was synthesized and rapidly crystallized by reacting mellitic acid, C-6(CO2H)(6), and BkBr3 center dot nH(2)O in an aqueous medium. Single crystal X-ray diffraction shows that the compound crystallizes as a three-dimensional framework isostructural with Pu(iii), Am(iii), and Cm(iii) mellitates. UV-vis-NIR spectroscopic studies as a function of pressure were performed using a diamond anvil cell and show that the 5f -> 5f transitions of Bk3+ display enhanced hypsochromic shifting when compared to other An(iii) mellitates.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Sperling, Joseph M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Beck, Nicholas UNSPECIFIED orcid.org/0000-0001-5687-192X UNSPECIFIED Scheibe, Benjamin UNSPECIFIED orcid.org/0000-0002-4665-6289 UNSPECIFIED Bai, Zhuanling UNSPECIFIED UNSPECIFIED UNSPECIFIED Brannon, Jacob UNSPECIFIED orcid.org/0000-0001-7786-127X UNSPECIFIED Gomez-Martinez, Daniela UNSPECIFIED UNSPECIFIED UNSPECIFIED Groedler, Dennis UNSPECIFIED UNSPECIFIED UNSPECIFIED Johnson, Jason A. UNSPECIFIED UNSPECIFIED UNSPECIFIED Lin, Xinsong UNSPECIFIED orcid.org/0000-0002-0605-3029 UNSPECIFIED Rotermund, Brian M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Albrecht-Schoenzart, Thomas E. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-669229
DOI:	10.1039/d1cc06958f
Journal or Publication Title:	Chem. Commun.
Volume:	58
Number:	13
Page Range:	S. 2200 - 2204
Date:	2022
Publisher:	ROYAL SOC CHEMISTRY
Place of Publication:	CAMBRIDGE
ISSN:	1364-548X
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language RADIOACTIVE DECAY; IONIC-RADII; ACTINIDE; LANTHANIDE; PLUTONIUM; SPECTRA; URANIUM Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/66922