Universität zu Köln

Belloche, A., Garrod, R. T., Zingsheim, O., Mueller, H. S. P. and Menten, K. M. (2022). Interstellar detection and chemical modeling of iso-propanol and its normal isomer. Astron. Astrophys., 662. LES ULIS CEDEX A: EDP SCIENCES S A. ISSN 1432-0746

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Abstract

Context. The detection of a branched alkyl molecule in the high-mass star forming protocluster Sagittarius (Sgr) B2(N) permitted by the advent of the Atacama Large Millimeter/submillimeter Array (ALMA) revealed a new dimension of interstellar chemistry. Astrochemical simulations subsequently predicted that beyond a certain degree of molecular complexity, branched molecules could even dominate over their straight-chain isomers. Aims. More generally, we aim to probe further the presence in the interstellar medium of complex organic molecules with the capacity to exhibit both a normal and iso form, via the attachment of a functional group to either a primary or secondary carbon atom. Methods. We used the imaging spectral line survey ReMoCA performed with ALMA at high angular resolution and the results of a recent spectroscopic study of propanol to search for the iso and normal isomers of this molecule in the hot molecular core Sgr B2(N2). We analyzed the interferometric spectra under the assumption of local thermodynamical equilibrium. We expanded the network of the astrochemical model MAGICKAL to explore the formation routes of propanol and put the observational results in a broader astrochemical context. Results. We report the first interstellar detection of iso-propanol, -C3H7OH, toward a position of Sgr B2(N2) that shows narrow linewidths. We also report the first secure detection of the normal isomer of propanol, n-C3H7OH, in a hot core. Iso-propanol is found to be nearly as abundant as normal-propanol, with an abundance ratio of 0.6 which is similar to the ratio of 0.4 that we obtained previously for iso- and normal-propyl cyanide in Sgr B2(N2) at lower angular resolution with our previous ALMA survey, EMoCA. The observational results are in good agreement with the outcomes of our astrochemical models, which indicate that the OH-radical addition to propylene in dust-grain ice mantles, driven by water photodissociation, can produce appropriate quantities of normal- and iso-propanol. The normal-to-iso ratio in Sgr B2(N2) may be a direct inheritance of the branching ratio of this reaction process. Conclusions. The detection of normal- and iso-propanol and their ratio indicate that the modest preference for the normal form of propyl cyanide determined previously may be a more general feature among similarly sized interstellar molecules. Detecting other pairs of interstellar organic molecules with a functional group attached either to a primary or secondary carbon may help in pinning down the processes that dominate in setting their normal-to-iso ratios. Butanol and its isomers would be the next obvious candidates in the alcohol family, but their detection in hot cores will be challenging.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Belloche, A. UNSPECIFIED UNSPECIFIED UNSPECIFIED Garrod, R. T. UNSPECIFIED UNSPECIFIED UNSPECIFIED Zingsheim, O. UNSPECIFIED UNSPECIFIED UNSPECIFIED Mueller, H. S. P. UNSPECIFIED UNSPECIFIED UNSPECIFIED Menten, K. M. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-673869
DOI:	10.1051/0004-6361/202243575
Journal or Publication Title:	Astron. Astrophys.
Volume:	662
Date:	2022
Publisher:	EDP SCIENCES S A
Place of Publication:	LES ULIS CEDEX A
ISSN:	1432-0746
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language SUBMILLIMETER-WAVE SPECTRUM; EXPLORING MOLECULAR COMPLEXITY; HYDROXYL RADICAL REACTIONS; KINETIC-DATA EVALUATION; GAS-PHASE KINETICS; MILLIMETER-WAVE; ORGANIC-MOLECULES; SGR B2(N); ADDITIONAL MEASUREMENTS; ATMOSPHERIC CHEMISTRY Multiple languages Astronomy & Astrophysics Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/67386