Universität zu Köln

Badea, Désirée ORCID: 0000-0002-8837-9988, Lenting, Christoph ORCID: 0000-0001-8374-5857, Hanrath, Michael ORCID: 0000-0003-3188-3961 and Bruns, Jörn ORCID: 0000-0002-8589-6154 (2025). Synthesis and Characterization of A3[ReO4][ReO3N] and A′2[ReO3N] (A = Rb, Cs; A′ = K, Cs). European Journal of Inorganic Chemistry, 28 (17). pp. 1-7. Wiley. ISSN 1434-1948

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Abstract

[Artikel-Nr.: e202500036] Crystallographically phase‐pure samples of A 3 [ReO 4 ][ReO 3 N] with A = Rb, Cs are obtained from the reaction of NH 4 [ReO 4 ] in an alkali metal hydroxide flux. Both compounds are isotypic to the known compound K 3 [ReO 4 ][ReO 3 N] and crystallize in the space group R m . [1] A ′ 2 [ReO 3 N] with A ′ = K, Cs are also synthesized from the respective alkali metal hydroxides, but with an increased amount of the nitrogen source via adding ammonium chloride to the starting mixture. K 2 [ReO 3 N] crystallizes in the space group C 2/ m , whereas Cs 2 [ReO 3 N] crystallizes in the space group Pnma . Along with the characterization of the four novel crystal structures, the experimental results are further supported by Raman spectroscopy and quantum chemical calculations.

Item Type:	Article
Creators:	Creators Email ORCID ORCID Put Code Badea, Désirée UNSPECIFIED https://orcid.org/0000-0002-8837-9988 UNSPECIFIED Lenting, Christoph UNSPECIFIED https://orcid.org/0000-0001-8374-5857 UNSPECIFIED Hanrath, Michael UNSPECIFIED https://orcid.org/0000-0003-3188-3961 UNSPECIFIED Bruns, Jörn UNSPECIFIED https://orcid.org/0000-0002-8589-6154 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-803632
Identification Number:	10.1002/ejic.202500036
Journal or Publication Title:	European Journal of Inorganic Chemistry
Volume:	28
Number:	17
Page Range:	pp. 1-7
Number of Pages:	7
Date:	17 June 2025
Publisher:	Wiley
ISSN:	1434-1948
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Biochemistry
Subjects:	Chemistry and allied sciences Life sciences
Uncontrolled Keywords:	Keywords Language flux ; oxoanion ; Raman spectroscopy quantum chemistry ; rhenium English
['eprint_fieldname_oa_funders' not defined]:	Publikationsfonds UzK
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/80363