Tavakoli, Ghazal ORCID: 0000-0001-9476-8448, Armstrong, Jessica E., Naapuri, Janne M., Deska, Jan ORCID: 0000-0003-4622-2365 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2019). Chemoenzymatic Hydrogen Production from Methanol through the Interplay of Metal Complexes and Biocatalysts. Chem.-Eur. J., 25 (26). S. 6474 - 6482. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

Microbial methylotrophic organisms can serve as great inspiration in the development of biomimetic strategies for the dehydrogenative conversion of C-1 molecules under ambient conditions. In this Concept article, a concise personal perspective on the recent advancements in the field of biomimetic catalytic models for methanol and formaldehyde conversion, in the presence and absence of enzymes and co-factors, towards the formation of hydrogen under ambient conditions is given. In particular, formaldehyde dehydrogenase mimics have been introduced in stand-alone C-1-interconversion networks. Recently, coupled systems with alcohol oxidase and dehydrogenase enzymes have been also developed for in situ formation and decomposition of formaldehyde and/or reduced/oxidized nicotinamide adenine dinucleotide (NADH/NAD+). Although C-1 molecules are already used in many industries for hydrogen production, these conceptual bio-inspired low-temperature energy conversion processes may lead one day to more efficient energy storage systems enabling renewable and sustainable hydrogen generation for hydrogen fuel cells under ambient conditions using C-1 molecules as fuels for mobile and miniaturized energy storage solutions in which harsh conditions like those in industrial plants are not applicable.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Tavakoli, GhazalUNSPECIFIEDorcid.org/0000-0001-9476-8448UNSPECIFIED
Armstrong, Jessica E.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Naapuri, Janne M.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Deska, JanUNSPECIFIEDorcid.org/0000-0003-4622-2365UNSPECIFIED
Prechtl, Martin H. G.UNSPECIFIEDorcid.org/0000-0003-2155-8006UNSPECIFIED
URN: urn:nbn:de:hbz:38-148459
DOI: 10.1002/chem.201806351
Journal or Publication Title: Chem.-Eur. J.
Volume: 25
Number: 26
Page Range: S. 6474 - 6482
Date: 2019
Publisher: WILEY-V C H VERLAG GMBH
Place of Publication: WEINHEIM
ISSN: 1521-3765
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
AQUEOUS FORMALDEHYDE; OXIDATION; NADH; RUTHENIUM; PATHWAYS; DEHYDROGENATION; METABOLISM; GENERATION; CATALYSTSMultiple languages
Chemistry, MultidisciplinaryMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/14845

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