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Siedenberg, Katharina, Strauss, Harald and Hoffmann, Elis J. (2016). Multiple sulfur isotope signature of early Archean oceanic crust, Isua (SW-Greenland). Precambrian Res., 283. S. 1 - 13. AMSTERDAM: ELSEVIER. ISSN 1872-7433

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Abstract

The Archean sulfur cycle was different from the present-day cycle, as the emission of volcanogenic sulfurous gases was the dominant process in the anoxic environment of the early Earth.This emitted sulfur exhibits mass-independently fractionated sulfur isotopes (MIF-S), resulting from photochemical reactions in the atmosphere, and it differs substantially from unfractionated sulfur in the mantle. So far, the main focus of multiple sulfur analyses (S-32, S-33, S-34 and S-36) was placed on the sedimentary part of the Archean sulfur cycle. In order to constrain the magmatic part of the sulfur cycle, we analyzed the sulfur isotopic composition of oceanic crustal rocks from the ca. 3.7-3.8 Ga Isua Supracrustal Belt (ISB). Differently altered samples were taken from two units:(1) the Undifferentiated Amphibolites (UA) and (2) the younger Amphibolites with Boninitic affinity (AB). The mean values are:delta S-34(CRS) = +0.01 +/- 0.65 parts per thousand (values range from -0.87 to 1.37%0; CRS = chromium-reducible sulfur), Delta S-33(CRS) = +0.02 +/- 0.12%0 (values range from -0.17 to 0.26 parts per thousand), Delta S-36(CRS) = -0.47 +/- 0.06 parts per thousand (values range from -0.56 to -0.38 parts per thousand). Thus, the mean isotope values support the assumption that the sulfur isotopic signature reflects the expected near-zero signature of their mantle origin. However, differences in Delta S-33(CRS) values are discernible and non-zero suggesting that different sources are contributing to the isotopic signature. An influence of alteration is excluded for all samples as different alteration-sensitive geochemical parameters do not show any correlation with the multiple sulfur isotope signatures. Further, it is unlikely that the small magnitudes in Delta S-33(CRS) are generated by microbial mass-dependent processes because of the narrow range of delta S-34(CRS) values. Possible sources contributing an atmospheric MIF-S signature include seawater sulfate (negative Delta S-33(CRS) values) through hydrothermal circulation, the assimilation of ocean floor sediments during the ascent of the melt and/or a mantle source contamination by subducted oceanic slab. (C) 2016 Elsevier B.V. All rights reserved.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Siedenberg, Katharina UNSPECIFIED UNSPECIFIED UNSPECIFIED Strauss, Harald UNSPECIFIED UNSPECIFIED UNSPECIFIED Hoffmann, Elis J. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-264847
DOI:	10.1016/j.precamres.2016.07.002
Journal or Publication Title:	Precambrian Res.
Volume:	283
Page Range:	S. 1 - 13
Date:	2016
Publisher:	ELSEVIER
Place of Publication:	AMSTERDAM
ISSN:	1872-7433
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language MICROBIAL SULFATE REDUCTION; SOUTHERN WEST GREENLAND; MASS-INDEPENDENT SULFUR; ITSAQ GNEISS COMPLEX; GREENSTONE-BELT; SUPRACRUSTAL BELT; GEOCHEMICAL EVIDENCE; METASEDIMENTARY ENCLAVES; ATMOSPHERIC SULFUR; PB-ISOTOPE Multiple languages Geosciences, Multidisciplinary Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/26484