Universität zu Köln

van der Waals, Dominic ORCID: 0000-0001-6847-8316, Heim, Leo E., Vallazza, Simona, Gedig, Christian, Deska, Jan ORCID: 0000-0003-4622-2365 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2016). Self-Sufficient Formaldehyde-to-Methanol Conversion by Organometallic Formaldehyde Dismutase Mimic. Chem.-Eur. J., 22 (33). S. 11568 - 11574. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

The catalytic networks of methylotrophic organisms, featuring redox enzymes for the activation of one-carbon moieties, can serve as great inspiration in the development of novel homogeneously catalyzed pathways for the interconversion of C-1 molecules at ambient conditions. An imidazolium-tagged arene-ruthenium complex was identified as an effective functional mimic of the bacterial formaldehyde dismutase, which provides a new and highly selective route for the conversion of formaldehyde to methanol in absence of any external reducing agents. Moreover, secondary amines are reductively methylated by the organometallic dismutase mimic in a redox self-sufficient manner with formaldehyde acting both as carbon source and reducing agent.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code van der Waals, Dominic UNSPECIFIED orcid.org/0000-0001-6847-8316 UNSPECIFIED Heim, Leo E. UNSPECIFIED UNSPECIFIED UNSPECIFIED Vallazza, Simona UNSPECIFIED UNSPECIFIED UNSPECIFIED Gedig, Christian UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-266713
DOI:	10.1002/chem.201602679
Journal or Publication Title:	Chem.-Eur. J.
Volume:	22
Number:	33
Page Range:	S. 11568 - 11574
Date:	2016
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3765
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language FORMIC-ACID; PSEUDOMONAS-PUTIDA; CARBON-DIOXIDE; CATALYTIC-HYDROGENATION; HOMOGENEOUS CATALYSIS; CO2 HYDROGENATION; DEHYDROGENASE; DISPROPORTIONATION; COMPLEXES; FORMATES Multiple languages Chemistry, Multidisciplinary Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/26671