Universität zu Köln

Voigt, Claudia, Klipsch, Swea, Herwartz, Daniel, Chong, Guillermo and Staubwasser, Michael (2020). The spatial distribution of soluble salts in the surface soil of the Atacama Desert and their relationship to hyperaridity. Glob. Planet. Change, 184. AMSTERDAM: ELSEVIER. ISSN 1872-6364

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Abstract

We systematically investigated the spatial distribution of sulfates, chlorides, and nitrates in Atacama Desert soils in order to identify their relationship to long-term aridity gradients and to secondary redistribution and phase transformation. Thin surface crusts, powdery surface material and subsurface concretions from up to 40 cm depth were sampled along several latitudinal transects between 19.5-25 degrees S and 68.5-70.5 degrees W. The samples were characterized by total soil chemical analysis (ICP-OES and spectrophotometric analysis) complemented by XRD and thermogravimetric analysis to determine contents of chloride, nitrate, and major elements along with gypsum and anhydrite abundance in Atacama Desert soils. Our results demonstrate that the spatial distribution of gypsum, anhydrite, halite, and nitrates in Atacama Desert soils is indeed linked to aridity gradients, but also sources, and secondary dissolution processes. Nitrates and chlorides are best preserved between 19 and 22 degrees S, which thus may constitute the long-term hyperarid core of the Atacama Desert. Remobilization within the soil is ubiquitous south of 22 degrees S, but generally also occurs on the debris fans prograding from the Precordillera into the Central Depression. A near-constant concentration ratio of Na/Cl = 0.83 - very similar to the sea water ratio - throughout the desert and concentration maxima within the reaches of coastal fog penetration below the altitude of 1200 m reveals that sea spray is the primary source of halite in Atacama Desert soils. Calcium sulfates dominate Atacama Desert soils. Deposition is primarily as gypsum, but anhydrite is abundant in the northern Central Depression between 19 and 22 degrees S. The apparent association of anhydrite with high concentrations of nitrate and chloride may point to a formation by dissolution and secondary reprecipitation from salt-concentrated fluids. The predominance of anhydrite in the Central Depression suggest geomorphology and water availability as additional factors remaining to be determined.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Voigt, Claudia UNSPECIFIED UNSPECIFIED UNSPECIFIED Klipsch, Swea UNSPECIFIED UNSPECIFIED UNSPECIFIED Herwartz, Daniel UNSPECIFIED UNSPECIFIED UNSPECIFIED Chong, Guillermo UNSPECIFIED UNSPECIFIED UNSPECIFIED Staubwasser, Michael UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-351991
DOI:	10.1016/j.gloplacha.2019.103077
Journal or Publication Title:	Glob. Planet. Change
Volume:	184
Date:	2020
Publisher:	ELSEVIER
Place of Publication:	AMSTERDAM
ISSN:	1872-6364
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language ATMOSPHERIC DEPOSITION; NITRATE DEPOSITS; TARAPACA REGION; NORTHERN CHILE; CLIMATE-CHANGE; HYPER-ARIDITY; FORE-ARC; ORIGIN; ANHYDRITE; GYPSUM Multiple languages Geography, Physical; Geosciences, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/35199