Wang, Qifang, Neudoerfl, Joerg-M. and Berkessel, Albrecht ORCID: 0000-0003-0470-7428
(2015).
Titanium cis-1,2-Diaminocyclohexane (cis-DACH) Salalen Catalysts for the Asymmetric Epoxidation of Terminal Non-Conjugated Olefins with Hydrogen Peroxide.
Chem.-Eur. J., 21 (1).
S. 247 - 255.
WEINHEIM:
WILEY-V C H VERLAG GMBH.
ISSN 1521-3765
Abstract
Chiral Ti salalen complexes catalyze the asymmetric epoxidation of terminal non-conjugated olefins with hydrogen peroxide. Modular ligands based on cis-1,2-diaminocyclohexane (cis-DACH) were developed, giving high yields and enantiomeric excesses (ee, up to 96%) at catalyst loadings as low as 0.1-0.5mol%, and even under solvent-free conditions.
Item Type: | Journal Article | ||||||||||||||||
Creators: |
|
||||||||||||||||
URN: | urn:nbn:de:hbz:38-414859 | ||||||||||||||||
DOI: | 10.1002/chem.201404639 | ||||||||||||||||
Journal or Publication Title: | Chem.-Eur. J. | ||||||||||||||||
Volume: | 21 | ||||||||||||||||
Number: | 1 | ||||||||||||||||
Page Range: | S. 247 - 255 | ||||||||||||||||
Date: | 2015 | ||||||||||||||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||||||||||||||
Place of Publication: | WEINHEIM | ||||||||||||||||
ISSN: | 1521-3765 | ||||||||||||||||
Language: | English | ||||||||||||||||
Faculty: | Faculty of Mathematics and Natural Sciences | ||||||||||||||||
Divisions: | Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Organic Chemistry | ||||||||||||||||
Subjects: | no entry | ||||||||||||||||
Uncontrolled Keywords: |
|
||||||||||||||||
Refereed: | Yes | ||||||||||||||||
URI: | http://kups.ub.uni-koeln.de/id/eprint/41485 |
Downloads
Downloads per month over past year
Altmetric
Export
Actions (login required)
![]() |
View Item |