Universität zu Köln

Liebig, Stefan, Paulus, Michael, Sternemann, Christian ORCID: 0000-0001-9415-1106 and Ruschewitz, Uwe ORCID: 0000-0002-6511-6894 (2013). CsNaC2, CsKC2, CsRbC2 - Syntheses and Crystal Structures of Three New Acetylides. Z. Anorg. Allg. Chem., 639 (15). S. 2804 - 2809. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749

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Abstract

Three new alkali metal acetylides CsNaC2, CsKC2, and CsRbC2 have been synthesized and characterized by means of synchrotron powder diffraction studies. As a new synthetic approach, the binary alkali metal acetylides were reacted at relatively low temperatures (200 degrees C). DSC measurements were performed to prove the general usability of this reaction. CsKC2 and CsRbC2 crystallize in a variant of the anti-PbCl2-type structure (Pnma, Z = 4), while for CsNaC2 a new structure type (Pbcm, Z = 4) is found.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Liebig, Stefan UNSPECIFIED UNSPECIFIED UNSPECIFIED Paulus, Michael UNSPECIFIED UNSPECIFIED UNSPECIFIED Sternemann, Christian UNSPECIFIED orcid.org/0000-0001-9415-1106 UNSPECIFIED Ruschewitz, Uwe UNSPECIFIED orcid.org/0000-0002-6511-6894 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-470799
DOI:	10.1002/zaac.201300147
Journal or Publication Title:	Z. Anorg. Allg. Chem.
Volume:	639
Number:	15
Page Range:	S. 2804 - 2809
Date:	2013
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3749
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language A(2)MC(2) Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/47079