Universität zu Köln

Lingen, Verena, Luening, Anna, Strauss, Christian, Pantenburg, Ingo, Deacon, Glen B., Klein, Axel ORCID: 0000-0003-0093-9619 and Meyer, Gerd ORCID: 0000-0003-1000-9001 (2013). Palladium Complexes with the SC6F4H-4 Ligand - Synthesis, Spectroscopy, and Structures. Eur. J. Inorg. Chem., 2013 (25). S. 4450 - 4459. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1099-0682

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Abstract

The reaction of HSC6F4H-4 or KSC6F4H-4 with the palladium(II) complexes [(NN)PdCl2] [NN = 2,2-bipyridine (bpy) or 1,10-phenanthroline (phen)] leads to the mononuclear palladium complexes [(NN)Pd(SC6F4H-4)(2)] or [(NN)PdCl(SC6F4H-4)], whereas the reaction with [(COD)PdCl2] (COD = 1,5-cyclooctadiene) results in the loss of COD and the formation of the oligonuclear species [Pd(SC6F4H-4)(2)](m). For NN = phen, the compound [(phen)(2)K(-phen)(2)K(phen)(2)][(4-HC6F4S)(2)Pd(-SC6F4H-4)(2)Pd(SC6F4H-4)(2)] containing a homoleptic dimeric dianionic Pd complex was also obtained. The reaction of KSC6F4H-4 with PdCl2 yielded K-2[Pd(SC6F4H-4)(4)]. The new compounds were analysed and characterised by single-crystal XRD, H-1 and F-19 NMR spectroscopy and IR spectroscopy. The UV/Vis absorption spectroscopy and electrochemistry of [(bpy)Pd(SC6F4H-4)(2)] have been investigated and are compared to those of the related Pt derivative [(bpy)Pt(SC6F5)(2)].

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Lingen, Verena UNSPECIFIED UNSPECIFIED UNSPECIFIED Luening, Anna UNSPECIFIED UNSPECIFIED UNSPECIFIED Strauss, Christian UNSPECIFIED UNSPECIFIED UNSPECIFIED Pantenburg, Ingo UNSPECIFIED UNSPECIFIED UNSPECIFIED Deacon, Glen B. UNSPECIFIED UNSPECIFIED UNSPECIFIED Klein, Axel UNSPECIFIED orcid.org/0000-0003-0093-9619 UNSPECIFIED Meyer, Gerd UNSPECIFIED orcid.org/0000-0003-1000-9001 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-476153
DOI:	10.1002/ejic.201300403
Journal or Publication Title:	Eur. J. Inorg. Chem.
Volume:	2013
Number:	25
Page Range:	S. 4450 - 4459
Date:	2013
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1099-0682
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language FLUORINATED BENZENETHIOLATE LIGANDS; EXCITED-STATE PROPERTIES; CATALYZED HECK REACTION; CRYSTAL-STRUCTURE; ORGANOMETALLIC CHEMISTRY; PHOSPHORUS LIGANDS; THIOLATE LIGANDS; PLATINUM(II); DERIVATIVES; PD Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/47615