Universität zu Köln

Schmidt, Christoph ORCID: 0000-0002-2309-3209, Pettke, Thomas ORCID: 0000-0002-5784-0639, Preusser, Frank, Rufer, Daniel ORCID: 0000-0001-8966-2737, Kasper, Haino Uwe and Hilgers, Alexandra (2012). Quantification and spatial distribution of dose rate relevant elements in silex used for luminescence dating. Quat. Geochronol., 12. S. 65 - 74. OXFORD: ELSEVIER SCI LTD. ISSN 1871-1014

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Abstract

Thermoluminescence (TL) is routinely used to date heated lithic artefacts which mostly consist of silex (a mixture of amorphous opal and microcrystalline chalcedony). Analytical investigations of bulk samples confirmed that these materials contain considerable concentrations of radioactive elements, generating an internal dose rate contribution. Common dosimetric models assume the latter to be homogeneous throughout the sample. If this assumption would prove invalid, this will result in systematic errors in the calculated age, especially in the course of so called 'hot spots' of alpha-emitters (and associated local changes in a-sensitivity) and the dose response characteristics of alpha-radiation. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of 22 silex samples are presented here, quantifying element concentrations at several tens analytical spots per sample. Along with radioactive elements (K, Rb, U, Th), another 21 major, minor and trace elements were measured in order to allow characterization of the impurities present in most of the samples. The dataset provides a detailed picture of the spatial distribution of radionuclides and hence of the uniformity of the internal alpha- and beta-dose rate. It is shown that the silex itself mostly contains low amounts of K (<0.1 wt.%), U (<1.0 mu g g(-1)) and Th (<0.4 mu g g(-1)), and dosimetrically negligible Rb concentrations. Systematically higher concentrations are obtained by ICP-MS measurements of the bulk samples. This matches with the finding that impurities (veins, inclusions) often yield significantly elevated radionuclide concentrations, up to two orders of magnitude higher than the silex values. These veins and inclusions, for example Ca or Mg carbonates and Fe-Mn-oxy-hydroxides, lead to steep gradients mainly in the internal alpha-radiation field. Alternative approaches are required to account for the non-uniform internal dose rate and improve the reliability of TL dates of problematic samples. (c) 2012 Elsevier B.V. All rights reserved.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Schmidt, Christoph UNSPECIFIED orcid.org/0000-0002-2309-3209 UNSPECIFIED Pettke, Thomas UNSPECIFIED orcid.org/0000-0002-5784-0639 UNSPECIFIED Preusser, Frank UNSPECIFIED UNSPECIFIED UNSPECIFIED Rufer, Daniel UNSPECIFIED orcid.org/0000-0001-8966-2737 UNSPECIFIED Kasper, Haino Uwe UNSPECIFIED UNSPECIFIED UNSPECIFIED Hilgers, Alexandra UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-481351
DOI:	10.1016/j.quageo.2012.05.006
Journal or Publication Title:	Quat. Geochronol.
Volume:	12
Page Range:	S. 65 - 74
Date:	2012
Publisher:	ELSEVIER SCI LTD
Place of Publication:	OXFORD
ISSN:	1871-1014
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language HEATED FLINT; ICP-MS; CAVE; CHRONOLOGY Multiple languages Geography, Physical; Geosciences, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/48135