Universität zu Köln

Boiko, Vladimir N., Filatov, Andrey A., Yagupolskii, Yurii L., Tyrra, Wieland, Naumann, Dieter, Pantenburg, Ingo, Fischer, Hendrik T. M. and Schulz, Frank (2011). A convenient synthetic route to 2,4,6-tris(chlorosulfonyl)- and 2,4,6-tris(fluorosulfonyl)phenol, aniline and chlorobenzene. J. Fluor. Chem., 132 (12). S. 1219 - 1227. LAUSANNE: ELSEVIER SCIENCE SA. ISSN 1873-3328

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Abstract

Convenient and preparative synthetic procedures of 2,4,6-tris(chlorosulfonyl)- and 2,4,6-tris(fluorosulfonyl)phenol, -chlorobenzene and -aniline have been elaborated. Chlorine exchange for fluorine by KF interaction on 2,4,6-tris(chlorosulfonyl)aniline and especially 2,4,6-tris(chlorosulfonyl)phenol proceeds easily and selectively under anhydrous conditions in dioxane. Unlike, 2,4,6-tris(chlorosulfonyl)chlorobenzene transformation requires the presence of water. On the basis of 2,4,6-tris(fluorosulfonyl)phenol and some of its salts, XRD measurements demonstrated the structural similarity to picric acid and its derivatives in the solid state. (C) 2011 Elsevier B.V. All rights reserved.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Boiko, Vladimir N. UNSPECIFIED UNSPECIFIED UNSPECIFIED Filatov, Andrey A. UNSPECIFIED UNSPECIFIED UNSPECIFIED Yagupolskii, Yurii L. UNSPECIFIED UNSPECIFIED UNSPECIFIED Tyrra, Wieland UNSPECIFIED UNSPECIFIED UNSPECIFIED Naumann, Dieter UNSPECIFIED UNSPECIFIED UNSPECIFIED Pantenburg, Ingo UNSPECIFIED UNSPECIFIED UNSPECIFIED Fischer, Hendrik T. M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Schulz, Frank UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-484608
DOI:	10.1016/j.jfluchem.2011.06.045
Journal or Publication Title:	J. Fluor. Chem.
Volume:	132
Number:	12
Page Range:	S. 1219 - 1227
Date:	2011
Publisher:	ELSEVIER SCIENCE SA
Place of Publication:	LAUSANNE
ISSN:	1873-3328
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language AROMATIC SULFONYL FLUORIDES; ANIONIC SIGMA-COMPLEXES; METAL PICRATES; DERIVATIVES; CHLORIDES Multiple languages Chemistry, Inorganic & Nuclear; Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/48460