Bikas, Rahman ORCID: 0000-0003-0078-7571, Monfared, Hassan Hosseini, Alami, Somayeh, Pantenburg, Ingo and Meyer, Gerd ORCID: 0000-0003-1000-9001 (2010). A Vanadyl(V) Complex with a Pincer-type Thiobis(phenolate) and an Acetylacetonate Co-ligand, VO(tbp)(acac). Z.Naturforsch.(B), 65 (12). S. 1457 - 1462. BERLIN: WALTER DE GRUYTER GMBH. ISSN 1865-7117
Full text not available from this repository.Abstract
A new vanadyl(V) complex with the tridentate, pincer-type O,S,O-ligand thiobis(phenolate), tbp, was synthesized from the reaction of vanadium(IV) oxide bis(acetylacetonate), VO(acac)(2), and 2,2'thio-bis(4-methylphenol), H(2)tbp, in refluxing methanol in high yield. Single-crystal X-ray diffraction structure analysis revealed for VO(tbp)(acac) that the vanadium atom is octahedrally coordinated with an O-5,S-donor environment where the thiobis(phenolate) ligand is O,S,O-bonded to the vanadyl(V) center facially in a tridentate dinegative fashion. Cyclic voltammetric experiments carried out with its solution in dimethyl sulfoxide revealed an irreversible peak at -0.768 V (vs. Ag/AgCl) relating to the V5+/V4+ reduction process.
Item Type: | Journal Article | ||||||||||||||||||||||||
Creators: |
|
||||||||||||||||||||||||
URN: | urn:nbn:de:hbz:38-490920 | ||||||||||||||||||||||||
DOI: | 10.1515/znb-2010-1208 | ||||||||||||||||||||||||
Journal or Publication Title: | Z.Naturforsch.(B) | ||||||||||||||||||||||||
Volume: | 65 | ||||||||||||||||||||||||
Number: | 12 | ||||||||||||||||||||||||
Page Range: | S. 1457 - 1462 | ||||||||||||||||||||||||
Date: | 2010 | ||||||||||||||||||||||||
Publisher: | WALTER DE GRUYTER GMBH | ||||||||||||||||||||||||
Place of Publication: | BERLIN | ||||||||||||||||||||||||
ISSN: | 1865-7117 | ||||||||||||||||||||||||
Language: | English | ||||||||||||||||||||||||
Faculty: | Unspecified | ||||||||||||||||||||||||
Divisions: | Unspecified | ||||||||||||||||||||||||
Subjects: | no entry | ||||||||||||||||||||||||
Uncontrolled Keywords: |
|
||||||||||||||||||||||||
URI: | http://kups.ub.uni-koeln.de/id/eprint/49092 |
Downloads
Downloads per month over past year
Altmetric
Export
Actions (login required)
View Item |