Hollmann, N., Hu, Z., Willers, T., Bohaty, L., Becker, P., Tanaka, A., Hsieh, H. H., Lin, H. -J., Chen, C. T. and Tjeng, L. H. (2010). Local symmetry and magnetic anisotropy in multiferroic MnWO4 and antiferromagnetic CoWO4 studied by soft x-ray absorption spectroscopy. Phys. Rev. B, 82 (18). COLLEGE PK: AMER PHYSICAL SOC. ISSN 2469-9969

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Abstract

Soft x-ray absorption experiments on the transition-metal L-2,L-3 edge of multiferroic MnWO4 and antiferromagnetic CoWO4 are presented. The observed linear polarization dependence, analyzed by full-multiplet calculations, is used to determine the ground-state wave function of the magnetic Mn2+ and Co2+ ions. The impact of the local structure and the spin-orbit coupling on the orbital moment is discussed in terms of the single-ion anisotropy. It is shown that the orbital moment in CoWO4 is responsible for the collinear antiferromagnetism, while the small size of spin-orbit coupling effects make spiral magnetic order in MnWO4 possible, enabling the material to be multiferroic.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Hollmann, N.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Hu, Z.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Willers, T.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Bohaty, L.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Becker, P.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Tanaka, A.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Hsieh, H. H.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Lin, H. -J.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Chen, C. T.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Tjeng, L. H.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-492249
DOI: 10.1103/PhysRevB.82.184429
Journal or Publication Title: Phys. Rev. B
Volume: 82
Number: 18
Date: 2010
Publisher: AMER PHYSICAL SOC
Place of Publication: COLLEGE PK
ISSN: 2469-9969
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
MAGNETOCRYSTALLINE ANISOTROPY; PHOTOEMISSIONMultiple languages
Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed MatterMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/49224

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