Universität zu Köln

Mayer, Matthias, Czaplik, Waldemar M. and Jacobi von Wangelin, Axel (2010). Practical Iron-Catalyzed Allylations of Aryl Grignard Reagents. Adv. Synth. Catal., 352 (13). S. 2147 - 2153. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1615-4169

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Abstract

An operationally simple iron-catalyzed reductive cross-coupling reaction between aryl halides and allyl electrophiles has been developed. The underlying domino process exhibits high versatility with respect to the allylic leaving group (acetate, tosylate, diethyl phosphate, methyl carbonate, trime-thylsilanolate, methanethiolate, chloride, bromide) and high economic and environmental sustainability with respect to the catalyst system (0.2-5 mol% tris(acetylacetonato) iron(III), ligand-free) and reaction conditions (tetrahydrofuran, 0 degrees C, 45 min).

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Mayer, Matthias UNSPECIFIED UNSPECIFIED UNSPECIFIED Czaplik, Waldemar M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Jacobi von Wangelin, Axel UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-496695
DOI:	10.1002/adsc.201000228
Journal or Publication Title:	Adv. Synth. Catal.
Volume:	352
Number:	13
Page Range:	S. 2147 - 2153
Date:	2010
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1615-4169
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CROSS-COUPLING REACTIONS; ALLYLIC AMINATION; ALKYL-HALIDES; ZINC REAGENTS; COMPLEXES; SUBSTITUTION; ACETATES; ISOMERIZATION; CARBONATES; MECHANISM Multiple languages Chemistry, Applied; Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/49669