Universität zu Köln

Groedler, Dennis, Weidemann, Martin L., Lichtenberg, Andreas ORCID: 0000-0003-2309-2123, Greven, Tobias ORCID: 0000-0002-8030-7293, Nickstadt, Robin, Haydo, Malek, Wickleder, Mathias ORCID: 0000-0002-8864-4227, Klein, Axel ORCID: 0000-0003-0093-9619, Johrendt, Dirk, Mathur, Sanjay, Zegke, Markus and Raauf, Aida (2022). Heterobimetallic uranyl(vi) alkoxides of lanthanoids: formation through simple ligand exchange. Chem. Commun., 58 (6). S. 835 - 839. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1364-548X

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Abstract

Lanthanoid and actinoid silylamides are versatile starting materials. Herein we show how a simple ligand exchange with tert-butanol leads to the formation of the first trimeric heterobimetallic uranyl(vi)-lanthanoid(iii) alkoxide complexes. The mu(3) coordination of the endogenous uranyl oxo atom results in a significant elongation of the bond length and a significant deviation from the linear uranyl arrangement.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Groedler, Dennis UNSPECIFIED UNSPECIFIED UNSPECIFIED Weidemann, Martin L. UNSPECIFIED UNSPECIFIED UNSPECIFIED Lichtenberg, Andreas UNSPECIFIED orcid.org/0000-0003-2309-2123 UNSPECIFIED Greven, Tobias UNSPECIFIED orcid.org/0000-0002-8030-7293 UNSPECIFIED Nickstadt, Robin UNSPECIFIED UNSPECIFIED UNSPECIFIED Haydo, Malek UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias UNSPECIFIED orcid.org/0000-0002-8864-4227 UNSPECIFIED Klein, Axel UNSPECIFIED orcid.org/0000-0003-0093-9619 UNSPECIFIED Johrendt, Dirk UNSPECIFIED UNSPECIFIED UNSPECIFIED Mathur, Sanjay UNSPECIFIED UNSPECIFIED UNSPECIFIED Zegke, Markus UNSPECIFIED UNSPECIFIED UNSPECIFIED Raauf, Aida UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-574596
DOI:	10.1039/d1cc05444a
Journal or Publication Title:	Chem. Commun.
Volume:	58
Number:	6
Page Range:	S. 835 - 839
Date:	2022
Publisher:	ROYAL SOC CHEMISTRY
Place of Publication:	CAMBRIDGE
ISSN:	1364-548X
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language HETEROMETALLIC COMPLEXES; URANIUM; REDUCTION; IONS; PU; NP Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/57459