Universität zu Köln

Haemmer, Matthias, Netzsch, Philip ORCID: 0000-0003-2537-2292, Klenner, Steffen, Neuschulz, Kai, Struckmann, Mona, Wickleder, Mathias S., Daub, Michael ORCID: 0000-0002-8414-3871, Hillebrecht, Harald ORCID: 0000-0003-2730-2677, Poettgen, Rainer and Hoeppe, Henning A. (2021). The tin sulfates Sn(SO4)(2) and Sn-2(SO4)(3): crystal structures, optical and thermal properties. Dalton Trans., 50 (37). S. 12913 - 12923. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1477-9234

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Abstract

We report the crystal structures of two tin(IV) sulfate polymorphs Sn(SO4)(2)-I (P2(1)/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, beta = 91.991(2)degrees, 4617 independent reflections, 104 refined parameters, wR(2) = 0.096) and Sn(SO4)(2)-II (P2(1)/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, beta = 92.496 (2)degrees, 3970 independent reflections, 101 refined parameters, wR(2) = 0.033). Moreover, the first heterovalent tin sulfate Sn-2(SO4)(3) is reported which adopts space group P (1) over bar (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, alpha = 89.007(7)degrees, beta = 86.381(7)degrees, gamma = 73.344(7)degrees, 1602 independent reflections, 152 refined parameters, wR(2) = 0.059). Finally, SnSO4 - the only tin sulfate with known crystal structure - was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and Sn-119 Mossbauer spectroscopy as well as thermogravimetry and compared.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Haemmer, Matthias UNSPECIFIED UNSPECIFIED UNSPECIFIED Netzsch, Philip UNSPECIFIED orcid.org/0000-0003-2537-2292 UNSPECIFIED Klenner, Steffen UNSPECIFIED UNSPECIFIED UNSPECIFIED Neuschulz, Kai UNSPECIFIED UNSPECIFIED UNSPECIFIED Struckmann, Mona UNSPECIFIED UNSPECIFIED UNSPECIFIED Wickleder, Mathias S. UNSPECIFIED UNSPECIFIED UNSPECIFIED Daub, Michael UNSPECIFIED orcid.org/0000-0002-8414-3871 UNSPECIFIED Hillebrecht, Harald UNSPECIFIED orcid.org/0000-0003-2730-2677 UNSPECIFIED Poettgen, Rainer UNSPECIFIED UNSPECIFIED UNSPECIFIED Hoeppe, Henning A. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-591066
DOI:	10.1039/d1dt02189c
Journal or Publication Title:	Dalton Trans.
Volume:	50
Number:	37
Page Range:	S. 12913 - 12923
Date:	2021
Publisher:	ROYAL SOC CHEMISTRY
Place of Publication:	CAMBRIDGE
ISSN:	1477-9234
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language IONIC-RADII; TIN(II); PHASE; SN; GE; STEREOCHEMISTRY; TRANSITION; FLUORIDES; MOSSBAUER; UNIQUE Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/59106