Universität zu Köln

Tavakoli, Ghazal ORCID: 0000-0001-9476-8448, Armstrong, Jessica E., Naapuri, Janne M., Deska, Jan ORCID: 0000-0003-4622-2365 and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2019). Chemoenzymatic Hydrogen Production from Methanol through the Interplay of Metal Complexes and Biocatalysts. Chem.-Eur. J., 25 (26). S. 6474 - 6482. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

Microbial methylotrophic organisms can serve as great inspiration in the development of biomimetic strategies for the dehydrogenative conversion of C-1 molecules under ambient conditions. In this Concept article, a concise personal perspective on the recent advancements in the field of biomimetic catalytic models for methanol and formaldehyde conversion, in the presence and absence of enzymes and co-factors, towards the formation of hydrogen under ambient conditions is given. In particular, formaldehyde dehydrogenase mimics have been introduced in stand-alone C-1-interconversion networks. Recently, coupled systems with alcohol oxidase and dehydrogenase enzymes have been also developed for in situ formation and decomposition of formaldehyde and/or reduced/oxidized nicotinamide adenine dinucleotide (NADH/NAD+). Although C-1 molecules are already used in many industries for hydrogen production, these conceptual bio-inspired low-temperature energy conversion processes may lead one day to more efficient energy storage systems enabling renewable and sustainable hydrogen generation for hydrogen fuel cells under ambient conditions using C-1 molecules as fuels for mobile and miniaturized energy storage solutions in which harsh conditions like those in industrial plants are not applicable.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Tavakoli, Ghazal UNSPECIFIED orcid.org/0000-0001-9476-8448 UNSPECIFIED Armstrong, Jessica E. UNSPECIFIED UNSPECIFIED UNSPECIFIED Naapuri, Janne M. UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-148459
DOI:	10.1002/chem.201806351
Journal or Publication Title:	Chem.-Eur. J.
Volume:	25
Number:	26
Page Range:	S. 6474 - 6482
Date:	2019
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3765
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language AQUEOUS FORMALDEHYDE; OXIDATION; NADH; RUTHENIUM; PATHWAYS; DEHYDROGENATION; METABOLISM; GENERATION; CATALYSTS Multiple languages Chemistry, Multidisciplinary Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/14845