Universität zu Köln

Tran, Uyen P. N., Oss, Giulia, Breugst, Martin ORCID: 0000-0003-0950-8858, Detmar, Eric, Pace, Domenic P., Liyanto, Kevin and Nguyen, Thanh V. (2019). Carbonyl-Olefin Metathesis Catalyzed by Molecular Iodine. ACS Catal., 9 (2). S. 912 - 927. WASHINGTON: AMER CHEMICAL SOC. ISSN 2155-5435

Full text not available from this repository.

Abstract

The carbonyl-olefin metathesis reaction could facilitate rapid functional group interconversion and allow construction of complicated organic structures. Herein, we demonstrate that elemental iodine, a very simple catalyst, can efficiently promote this chemical transformation under mild reaction conditions. Our mechanistic studies revealed intriguing aspects of the activation mode via molecular iodine and the iodonium ion that could change the previously established perception of catalyst and substrate design for the carbonyl-olefin metathesis reaction.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Tran, Uyen P. N. UNSPECIFIED UNSPECIFIED UNSPECIFIED Oss, Giulia UNSPECIFIED UNSPECIFIED UNSPECIFIED Breugst, Martin UNSPECIFIED orcid.org/0000-0003-0950-8858 UNSPECIFIED Detmar, Eric UNSPECIFIED UNSPECIFIED UNSPECIFIED Pace, Domenic P. UNSPECIFIED UNSPECIFIED UNSPECIFIED Liyanto, Kevin UNSPECIFIED UNSPECIFIED UNSPECIFIED Nguyen, Thanh V. UNSPECIFIED UNSPECIFIED UNSPECIFIED
URN:	urn:nbn:de:hbz:38-157716
DOI:	10.1021/acscatal.8b03769
Journal or Publication Title:	ACS Catal.
Volume:	9
Number:	2
Page Range:	S. 912 - 927
Date:	2019
Publisher:	AMER CHEMICAL SOC
Place of Publication:	WASHINGTON
ISSN:	2155-5435
Language:	English
Faculty:	Faculty of Mathematics and Natural Sciences
Divisions:	Faculty of Mathematics and Natural Sciences > Department of Chemistry > Institute of Organic Chemistry
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language ENOL ETHERS; ACTIVATION; ENERGIES; MECHANISM; ALCOHOLS; PYRIDINE; ESTER; SALTS Multiple languages Chemistry, Physical Multiple languages
Refereed:	Yes
URI:	http://kups.ub.uni-koeln.de/id/eprint/15771