Trincado, Monica, Grutzmacher, Hansjorg and Prechtl, Martin H. G. (2018). CO2-based hydrogen storage - Hydrogen generation from formaldehyde/water. J. Taibah Univ. Med. Soc., 3 (5). BERLIN: WALTER DE GRUYTER GMBH. ISSN 2365-659X

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Abstract

Formaldehyde (CH2O) is the simplest and most significant industrially produced aldehyde. The global demand is about 30 megatons annually. Industrially it is produced by oxidation of methanol under energy intensive conditions. More recently, new fields of application for the use of formaldehyde and its derivatives as, i.e. cross-linker for resins or disinfectant, have been suggested. Dialkoxymethane has been envisioned as a combustion fuel for conventional engines or aqueous formaldehyde and paraformaldehyde may act as a liquid organic hydrogen carrier molecule (LOHC) for hydrogen generation to be used for hydrogen fuel cells. For the realization of these processes, it requires less energy-intensive technologies for the synthesis of formaldehyde. This overview summarizes the recent developments in low-temperature reductive synthesis of formaldehyde and its derivatives and low-temperature formaldehyde reforming. These aspects are important for the future demands on modern societies' energy management, in the form of a methanol and hydrogen economy, and the required formaldehyde feedstock for the manufacture of many formaldehyde-based daily products.

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Trincado, MonicaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Grutzmacher, HansjorgUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Prechtl, Martin H. G.UNSPECIFIEDUNSPECIFIEDUNSPECIFIED
URN: urn:nbn:de:hbz:38-187215
DOI: 10.1515/psr-2017-0013
Journal or Publication Title: J. Taibah Univ. Med. Soc.
Volume: 3
Number: 5
Date: 2018
Publisher: WALTER DE GRUYTER GMBH
Place of Publication: BERLIN
ISSN: 2365-659X
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
CARBON-DIOXIDE; METHANOL DEHYDROGENATION; PHOTOCATALYTIC REDUCTION; AQUEOUS FORMALDEHYDE; ROOM-TEMPERATURE; PINCER CATALYST; FORMIC-ACID; CO2; WATER; EFFICIENTMultiple languages
Multidisciplinary SciencesMultiple languages
Refereed: Yes
URI: http://kups.ub.uni-koeln.de/id/eprint/18721

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