Universität zu Köln

Bruns, Joern, Hoeppe, Henning A., Daub, Michael ORCID: 0000-0002-8414-3871, Hillebrecht, Harald and Huppertz, Hubert ORCID: 0000-0002-2098-6087 (2020). Borosulfates-Synthesis and Structural Chemistry of Silicate Analogue Compounds. Chem.-Eur. J., 26 (36). S. 7966 - 7981. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

Borosulfates are oxoanionic compounds consisting of condensed sulfur- and boron-centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in SO3-enriched sulfuric acid, or from reactions with the superacid H[B(HSO4)(4)]. The crystal structures are very similar to those of the corresponding class of silicates and their substitution variants, especially regarding the typical structural motif of corner-sharing tetrahedra. However, the borosulfates are supposed to be even more versatile, because (BO3) units might also be part of the anionic network. The following article deals with detailed reports on the different synthesis strategies, the crystal chemistry of borosulfates in comparison to silicates, and their hitherto identified properties.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Bruns, Joern UNSPECIFIED UNSPECIFIED UNSPECIFIED Hoeppe, Henning A. UNSPECIFIED UNSPECIFIED UNSPECIFIED Daub, Michael UNSPECIFIED orcid.org/0000-0002-8414-3871 UNSPECIFIED Hillebrecht, Harald UNSPECIFIED UNSPECIFIED UNSPECIFIED Huppertz, Hubert UNSPECIFIED orcid.org/0000-0002-2098-6087 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-334467
DOI:	10.1002/chem.201905449
Journal or Publication Title:	Chem.-Eur. J.
Volume:	26
Number:	36
Page Range:	S. 7966 - 7981
Date:	2020
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3765
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language CRYSTAL-STRUCTURE; ANION; BOROPHOSPHATES; ALKALI; UNIQUE; ACID; M=SI; NA; SR; GE Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/33446