Universität zu Köln

Blume, Fabian, Albeiruty, Mhd Haitham and Deska, Jan ORCID: 0000-0003-4622-2365 (2015). Alkylative Amination of Biogenic Furans through Imine-to-Azaallyl Anion Umpolung. Synthesis, 47 (14). S. 2093 - 2100. STUTTGART: GEORG THIEME VERLAG KG. ISSN 1437-210X

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Abstract

Starting from biogenic furfurals, an operationally simple and scalable condensation-umpolung-alkylation protocol was employed in the synthesis of racemic furfurylamines. Subsequent enzymatic kinetic resolution by -transaminase or lipase biocatalysts allows for the preparation of functionalized heterocyclic building blocks from biogenic base chemicals in optically pure form.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Blume, Fabian UNSPECIFIED UNSPECIFIED UNSPECIFIED Albeiruty, Mhd Haitham UNSPECIFIED UNSPECIFIED UNSPECIFIED Deska, Jan UNSPECIFIED orcid.org/0000-0003-4622-2365 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-399697
DOI:	10.1055/s-0034-1380201
Journal or Publication Title:	Synthesis
Volume:	47
Number:	14
Page Range:	S. 2093 - 2100
Date:	2015
Publisher:	GEORG THIEME VERLAG KG
Place of Publication:	STUTTGART
ISSN:	1437-210X
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language ASYMMETRIC-SYNTHESIS; BUILDING-BLOCKS; REARRANGEMENT; ARYLATION Multiple languages Chemistry, Organic Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/39969