Universität zu Köln

Choi, Jong-Hoo ORCID: 0000-0001-7938-8420, Schloerer, Nils E., Berger, Josefine and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2014). Synthesis and characterisation of ruthenium dihydrogen complexes and their reactivity towards B-H bonds. Dalton Trans., 43 (1). S. 290 - 300. CAMBRIDGE: ROYAL SOC CHEMISTRY. ISSN 1477-9234

Full text not available from this repository.

Abstract

In this paper the synthesis and characterisation of ruthenium dihydrogen complexes bearing rigid aliphatic PNP pincer-type ligands are described. As one result hydride complexes were synthesised in good to high yields by a one-pot direct hydrogenation reaction. As another finding the dihydrogen complex, stabilised with a N-Me group in the ligand frame, can be converted with dimethylamine borane into a rare sigma-boron complex [RuH2(BH3)(Me-PNP)] with rapid B-N decoupling. Additionally, we present the first mass spectrometric analysis of the synthesised sigma-complexes via liquid injection field desorption/ionisation technique (LIFDI-MS).

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Choi, Jong-Hoo UNSPECIFIED orcid.org/0000-0001-7938-8420 UNSPECIFIED Schloerer, Nils E. UNSPECIFIED UNSPECIFIED UNSPECIFIED Berger, Josefine UNSPECIFIED UNSPECIFIED UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-452823
DOI:	10.1039/c3dt52037d
Journal or Publication Title:	Dalton Trans.
Volume:	43
Number:	1
Page Range:	S. 290 - 300
Date:	2014
Publisher:	ROYAL SOC CHEMISTRY
Place of Publication:	CAMBRIDGE
ISSN:	1477-9234
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language BASE-FREE CONDITIONS; HYDRIDE COMPLEXES; PINCER COMPLEXES; METAL-DIHYDROGEN; AMINE-BORANES; 1ST EXAMPLES; HYDROGENATION; H-2; CATALYST; DEHYDROGENATION Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/45282